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. 2025 Jun 25;125(14):6609–6652. doi: 10.1021/acs.chemrev.4c01014

6. Characteristic Quantum Threshold Temperatures T Q above which Semiclassical Methods Hold, as Derived by Julienne and Mies for Collisions of Species in Specified States Subject to van der Waals Potentials of Force Power n .

Species State n T Q
H + H Σ1g+ 6 20 K
He(S3)+He(S3) Σ1g+ 6 100 mK
Cs + Cs Σ1g+ 6 300 μK
Na + Na Σ1g+ 6 10 mK
Na(P23/2)+Na(P23/2) 1 u 5 740 μK
Na(P23/2)+Na 0 u 3 1 nK
a

Note T Q occurs in the ultracold regime for collisions of Cs + Cs, Na(P23/2)+Na(P23/2) , and Na(P23/2)+Na and in the cold regime for He(S3)+He(S3) and Na + Na. Reproduced with permission from ref . Copyright Optical Society of America.