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. 2002 Jun 4;99(12):7848–7853. doi: 10.1073/pnas.122154899

Table 3.

O2-based global carbon budget 1990–2000

Budget item Pg of C yr−1
Manning (33) Revised budget
Fossil-fuel burning 6.33  ± 0.4 6.33  ± 0.4
Atmospheric CO2 increase 3.21  ± 0.1 3.21  ± 0.1
Total ocean CO2 sink 1.68  ± 0.5 1.86  ± 0.6
Total land CO2 sink 1.44  ± 0.7 1.26  ± 0.8

Budgets are based on the decadal trend in atmospheric O2/N2 ratio at two northern hemisphere stations in the Scripps O2/N2 network. Manning (33) assumes Z = 0.16 ± 0.16 × 1014 mol of O2 yr−1; revised budget assumes 0.29 ± 0.4 × 1014 mol of O2 yr−1 (see text). Budgets differ in assumed ocean warming rate, and in assumed oceanic O2 outgassing per unit warming. Both budgets allow for outgassing of N2 (which affects the observed O2/N2 ratio) at a rate based on N2 solubility of 2.2 nmol of N2 per J of warming.