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. 2025 Jul 16;129(29):7593–7601. doi: 10.1021/acs.jpcb.5c03338

3. Activation Energies (ΔG , in kcal mol–1), Individual (k i, in M–1 s–1), and Molar Fraction-Corrected Total Reaction Rates (k DPPH, in M–1 s–1) of Reaction between Studies Species and DPPH Radical.

compound position ΔG ≠* k i k total k DPPH
Gspt C3 24.4 5.06 × 10–3 3.58 × 102  
  C7 21.3 4.92 × 10–3    
  C8 19.9 6.10 × 100    
  C3 24.7 5.05 × 10–6    
  SET 14.0 3.52 × 102    
Gsp C3 26.7 3.88 × 10–7 1.97 × 10–1  
  C4 24.3 2.07 × 10–5    
  SET 18.4 1.97 × 10–1    
Hbf C4 26.1 6.84 × 10–7 1.02 × 100 2.26 × 101
  SET 17.1 1.91 × 100  
Hbf C3 24.5 3.17 × 101 2.16 × 101  
  C4 25.3 3.70 × 10–6  
  SET 15.2 4.62 × 101