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. 2025 Jul 14;27(29):7779–7784. doi: 10.1021/acs.orglett.5c02038

2. Kinetic Parameters for the Photooxidation of DMA, Including the Observed Rate Constant (k obs) and Singlet Molecular Oxygen Quantum Yield (ΦΔ) in DMF.

  TPP 6a 8a
kDMFobs (s–1) (3.2 ± 0.2) × 10–3 (3.1 ± 0.2) × 10–3 (3.3 ± 0.2) × 10–3
ΦΔ 0.64 0.62 ± 0.04 0.66 ± 0.04