1. Recent Studies on Mechanosynthesis of Organic Membrane Building Blocks with Their Environmental Implications and Performance.

	name	mechanosynthesis method	reaction time (min)	yield	additive/solvent used	SBET (m2/g)	refs
metal–organic framework	CuBTC	planetary mill	60	50–60%		1638
	MOF-303	planetary mill	180	50–60%	H2O	1180
	MOF-801	mixer mill	90	87 mg	H2O	540
	MOF-804	mixer mill	90	108 mg	H2O	755
	UiO-66	mixer mill	120	95 mg	H2O	1145
	UiO-66-NH2	mixer mill	90	111 mg	H2O	815
	UiO-66-NH2	planetary mill	90	11.3 g	H2O	885
	UiO-66-NH2	twin screw extrusion	1.4 kg/h		methanol	610
	ZIF-8	planetary mill	70	50–60%		1609
	ZIF-9	hand-grinding		∼10 mg	ethanol
	ZIF-UC-6	mixer mill	30		DMF	504
covalent organic framework	COF-1	mixer mill	45	76 mg	mesitylene + dioxane/THF	680
	COF-102	mixer mill	45	50 mg	mesitylene + dioxane/THF	2600
	DMTP-TPB	mixer mill	60	0.9 g, 83%	acetic acid + acetonitrile	1554
	Tp+Azo	hand-grinding	15		p-toluenesulfonic acid	1707
	Tp+BD-(SO3H)2	hand-grinding	15	72%		37
	Tp+Pa-1+MCNT	hand-grinding	25		p-toluenesulfonic acid + H2O	218
	Tp+Pa-1+nanocellulose	ball mill	20		p-toluenesulfonic acid + H2O	247
polymer of intrinsic microporosity	PIM-1	mixer mill	15	0.9 g, 98%		520
	PIM-1	planetary mill	20			545
	PIM-1	planetary mill	60			856
	PIM-4	mixer mill	15			179

^a S _BET: Brunauer–Emmett–Teller (BET) surface area.