Table 2.
Factors affecting fire and explosion hazards posed by hydrogen, methane, propane, and acetylene at atmospheric conditions (
1 atm and
298 K).
| Factor | Hydrogen value | Ref. | Methane value | Ref. | Propane value | Ref. | Acetylene value | Ref. |
|---|---|---|---|---|---|---|---|---|
| LFL (V% fuel in air) | 4.2 | 31 | 5 | 31 | 2.1 | 31 | 2.6 | 31 |
| UFL (V% fuel in air) | 74 | 31 | 14.9 | 31 | 9.5 | 31 | 80 | 31 |
| MOC (V% oxygen) | 4 | 31 | 12 | 31 | 11.6 | 31 | 6.2 | 31 |
| Autoignition temperature (K) | 858 | 36 | 813 | 37 | 757 | 38 | 578.15 | 39 |
| Minimum spark ignition energy (mJ) | 0.02 | 40 | 0.29 | 40 | 0.48 | 41 | 0.019 | 32 |
Density (kg/ ) |
0.083 | 42 | 0.657 | 43 | 1.832 | 44 | 1.092 | 39 |
| Molecular size (nm) | 0.29 | 45 | 0.38 | 45 | 0.45 | 46 | 0.33 | 47 |
| Quenching distance (mm) | 0.64 | 48 | 2.03 | 48 | 2.0 | 49 | 0.53 | 50 |
| Boiling point (K) | 20.4 | 31 | 111.7 | 31 | 231.1 | 31 | 189.2 | 31 |
| Flame speed at equivalence ratio of 1 (cm/s) | 207 | 48 | 36 | 48 |
40.1 |
51 |
127.9 |
33 |
| LHV (MJ/kg) | 119.9 | 52 | 48.6 | 53 | 46.4 | 54 | 48.2 | 55 |
| Adiabatic flame temperature in air (K) | 2376 | 56 | 2223 | 56 | 2253 | 57 | 2500 | 58 |
Deflagration index (bar m/s) |
638 | 59 | 46 | 59 | 76 | 59 | 42 | 60 |
Thermal conductivity (W/(m K)) |
182.0
|
40 | 34.0
|
40 | 18.5
|
61 | 21.4
|
61 |












