. 2025 Jul 31;11(8):4694–4713. doi: 10.1021/acsbiomaterials.5c00908

2. Antiadhesive and Antibacterial Materials Obtained by Glass Modification Using RDRP Techniques.

No.	Material	Technique	Monomer	Polymerization conditions
1	Glass	SI-ATRP	METAC SPMA HEMA	Initiator: chlorosilane 3- (trichlorosilyl)propyl 2-bromo-2-methylpropanoate
				Catalyst: CuBr/2,2’-bipyridine
				Argon atmosphere
				Solvent: H₂O/isopropanol (synthesis of PMETAC), H₂O/MeOH (synthesis of PSPMA and PHEMA)
2	Glass	SI-ATRP	MCP HEMA	Initiator: α-bromoisobutyryl bromide
				Catalyst: CuBr/bipyridine
				Nitrogen atmosphere
				Solvent: H₂O/MeOH
				Temperature: 25 °C
3	Glass	SI-ATRP	NAGA NAG	Initiator: α-bromoisobutyryl bromide
				Catalyst: CuBr/CuBr₂/PMDETA
				Nitrogen atmosphere
				Solvent: H₂O
				Temperature: 25 °C
4	Glass	SI-ATRP	SBMA CBMA	Initiator: 2-bromo-2-methyl-N-3-[(triethoxysilyl)propyl]propenamide
				Catalyst: CuBr/2,2’-bipyridine
				Nitrogen atmosphere
				Solvent: H₂O/MeOH
5	Glass Silicon	ATRP Click-chemistry	VBBI⁺ Tf₂N^– FMA	Initiator: 3- azidopropyl 2-bromo-2-methylpropanoate, 3-(acetylthio)propyl 2-bromo-2-methylpropanoate
				Catalyst: CuBr/CuBr₂/PMDETA
				Nitrogen atmosphere
				Solvent: butyronitrile
				Temperature: 90 °C
6	Glass	SI-ARGET ATRP	DMAEMA	Initiator: α-bromoisobutyryl bromide, ethyl α-bromoisobutyrate
				Catalyst: CuBr₂/TPMA
				Air atmosphere
				Solvent: H₂O
				Reducing agent: glucose, fructose
				Temperature: RT
7	Glass Silicon Gold PDMS	SI-RAFT	PMOXA-MA 4VP	Initiator: 2, 2’-azobis(isobutyronitrile)
				Chain transfer agent: S-1-dodecyl-S’-(α,α’-dimethyl-α’’-acetic acid) trithiocarbonate
				Vacuum atmosphere
				Solvent: tert-butanol
				Temperature: 80 °C