Table 3.
Parameters obtained via EEC for the EIS data for al immersed in 0.5 M H2SO4 without and with Vanillin as corrosion inhibitor.
| Cinh (mM) | Rs (Ω cm2) | CPEdl (×10− 5, F cm− 2) | n dl | Rct (Ω cm2) | L (H cm2) | RL (Ω cm2) | CPEinh (×10− 5, F cm− 2) | n inh | Rinh (Ω cm2) | Rp (Ω cm2) | %IE |
|---|---|---|---|---|---|---|---|---|---|---|---|
| 25 °C | |||||||||||
| 0 | 9.17 | 1.94 | 0.9 | 702 | 53.51 | 73.94 | 2.29 × 10− 8 | 0.4 | 17.93 | 803.05 | |
| 2 | 4.78 | 9.20 | 0.9 | 1200 | 229.5 | 334.82 | 1.06 × 10− 5 | 0.8 | 1626.00 | 3165.58 | 75 |
| 4 | 4.86 | 1.57 | 0.9 | 713.8 | 66.71 | 106.91 | 1.06 × 10− 4 | 0.8 | 228.00 | 1053.56 | 24 |
| 6 | 4.75 | 1.10 | 0.9 | 970.4 | 102.6 | 173.60 | 9.01 × 10− 5 | 0.8 | 224.40 | 1373.15 | 42 |
| 8 | 8.16 | 1.14 | 0.9 | 751.9 | 78.47 | 130.30 | 1.06 × 10− 4 | 0.6 | 401.70 | 1292.06 | 38 |
| 10 | 62.15 | 1.46 | 0.9 | 323 | 266.1 | 291.13 | 5.87 × 10− 7 | 0.8 | 1867.00 | 2543.25 | 68 |
| 40 °C | |||||||||||
| 0 | 2.70 | 1.49 | 0.9 | 25.93 | 1.446 | 11.24 | 1.87 × 10− 6 | 0.9 | 131.50 | 171.374 | |
| 2 | 3.64 | 5.58 | 0.9 | 1307 | 42.77 | 353.8 | 2.72 × 10− 7 | 0.4 | 788.10 | 2452.55 | 93 |
| 4 | 2.55 | 1.30 | 0.9 | 11.69 | 4.25 | 27.77 | 3.99 × 10− 8 | 0.4 | 249.70 | 291.75 | 41 |
| 6 | 2.47 | 1.36 | 0.9 | 23 | 13.9 | 169.5 | 1.34 × 10− 7 | 0.4 | 745.50 | 940.47 | 82 |
| 8 | 2.95 | 1.33 | 0.9 | 23 | 3.927 | 18.14 | 1.74 × 10− 7 | 0.3 | 288.50 | 332.60 | 48 |
| 10 | 2.51 | 1.36 | 0.9 | 40.8 | 12.82 | 54.04 | 6.55 × 10− 9 | 0.3 | 444.40 | 541.75 | 68 |
| 60 °C | |||||||||||
| 0 | 7.47 | 1.47 | 0.9 | 102.60 | 1.31 | 15.34 | 1.46 × 10− 2 | 0.4 | 39.74 | 165.15 | |
| 2 | 3.03 | 1.02 | 0.9 | 60.22 | 2.81 | 17.93 | 2.37 × 10− 5 | 0.7 | 207.6 | 288.78 | 43 |
| 4 | 10.37 | 1.77 | 0.9 | 198.02 | 14.3 | 27.58 | 2.45 × 10− 2 | 0.4 | 23.45 | 259.42 | 36 |
| 6 | 2.36 | 1.93 | 0.9 | 188.70 | 1.60 | 16.57 | 5.27 × 10− 2 | 0.4 | 52.33 | 259.96 | 36 |
| 8 | 2.97 | 1.85 | 0.9 | 89.41 | 3.32 | 8.02 | 9.58 × 10− 2 | 0.4 | 22.76 | 123.17 | – |
| 10 | 2.14 | 7.92 | 0.9 | 16.00 | 3.25 | 43.74 | 2.67 × 10− 7 | 0.9 | 228.3 | 290.18 | 43 |