Table 3.
Contamination Factor (Cf), Potetnial Ecological Risk Indices (Eri), Enrichment Factors (EF), Geo-accumulation Factor (lgeo), and the partition coefficient (Kd) of heavy metals (HM) in sediment samples collected from three sites (Indus Delta, Sandspit and, Miani Hor) in three different seasons (monsoon, post-monsoon and pre-monsoon).
| HM | Sandspit | Miani Hor | Indus Delta | ||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Cf | Eri | EF | lgeo | Kd | Cf | Eri | EF | lgeo | Kd | Cf | Eri | EF | lgeo | Kd | |
| Monsoon | |||||||||||||||
| Al | – | – | 0.012489 | − 12.11 | 1.19 | – | – | 0.005764 | − 13.606 | 1.03 | – | – | 0.020214 | − 12.08 | 2.91 |
| As | 1.367 | 13.667 | 57.84424 | 0.072 | 0.69 | 0.907 | 9.067 | 50.14749 | − 0.52 | 0.77 | 1.073 | 10.733 | 72.26212 | − 0.276 | 0.83 |
| Cd | 2.800 | 84.000 | 244.5448 | 2.152 | 1.17 | 1.500 | 45.000 | 171.1968 | 1.252 | 1.32 | 0.750 | 22.500 | 104.1934 | 0.252 | 1.17 |
| Cr | 0.307 | 0.613 | 11.24906 | − 2.29 | 0.56 | 0.029 | 0.058 | 1.379466 | − 5.704 | 0.61 | 0.010 | 0.020 | 0.570517 | − 7.261 | 0.64 |
| Cu | 0.112 | 0.560 | 0.82167 | − 6.065 | 1.23 | 0.036 | 0.182 | 0.348968 | − 7.687 | 1.07 | 0.038 | 0.188 | 0.438779 | − 7.64 | 1.23 |
| Fe | – | – | 1 | − 5.782 | 40.67 | – | – | 1 | − 6.168 | 1397.94 | – | – | 1 | − 6.452 | 790.07 |
| Hg | 51.200 | 2048.000 | 1173.815 | 4.415 | 0.78 | 44.400 | 1776.000 | 1330.199 | 4.209 | 0.82 | 52.400 | 2096.000 | 1910.907 | 4.448 | 0.82 |
| Pb | 0.306 | 1.529 | 9.812359 | − 2.487 | 1.35 | 0.025 | 0.124 | 1.036597 | − 6.12 | 1.03 | 0.015 | 0.074 | 0.751234 | − 6.864 | 1.18 |
| Se | – | – | 13.59381 | − 2.017 | 0.73 | – | – | 6.203366 | − 3.535 | 0.79 | – | – | 20.59352 | − 2.087 | 0.75 |
| Zn | 0.029 | 0.029 | 1.111567 | − 5.629 | 1.04 | 0.008 | 0.008 | 0.386386 | − 7.54 | 1.34 | 0.006 | 0.006 | 0.381916 | − 7.84 | 1.26 |
| RI | 2148 | 1830 | 2129 | ||||||||||||
| Post-monsoon | |||||||||||||||
| Al | – | – | 0.010872 | − 12.266 | 1.47 | – | – | 0.008265 | − 13.15 | 1.13 | – | – | 0.024584 | − 11.89 | 5.01 |
| As | 1.120 | 11.200 | 46.10318 | − 0.215 | 0.79 | 0.960 | 9.600 | 55.72755 | − 0.437 | 0.79 | 1.020 | 10.200 | 73.20574 | − 0.35 | 0.82 |
| Cd | 3.000 | 90.000 | 254.822 | 2.252 | 1.44 | 1.770 | 53.100 | 212.019 | 1.49 | 2.01 | 0.920 | 27.600 | 136.2497 | 0.546 | 1.96 |
| Cr | 0.390 | 0.780 | 13.91328 | − 1.943 | 0.81 | 0.032 | 0.064 | 1.598727 | − 5.561 | 0.77 | 0.013 | 0.026 | 0.79479 | − 6.875 | 1.16 |
| Cu | 0.096 | 0.480 | 0.684962 | − 6.288 | 1.93 | 0.040 | 0.202 | 0.406502 | − 7.536 | 1.96 | 0.041 | 0.203 | 0.505072 | − 7.529 | 1.83 |
| Fe | – | – | 1 | − 5.742 | 39.96 | – | – | 1 | − 6.238 | 1538.10 | – | – | 1 | − 6.544 | 900.86 |
| Hg | 43.200 | 1728.000 | 963.2272 | 4.16 | 0.73 | 43.200 | 1728.000 | 1358.359 | 4.17 | 0.90 | 46.000 | 1840.000 | 1788.278 | 4.261 | 0.83 |
| Pb | 0.366 | 1.829 | 11.41603 | − 2.229 | 2.39 | 0.030 | 0.150 | 1.320627 | − 5.837 | 1.51 | 0.021 | 0.106 | 1.150718 | − 6.341 | 1.87 |
| Se | 14.27003 | − 1.907 | 1.09 | – | – | 7.694409 | − 3.294 | 1.13 | – | – | 29.27104 | − 1.672 | 1.14 | ||
| Zn | 0.033 | 0.033 | 1.232412 | − 5.44 | 1.58 | 0.010 | 0.010 | 0.52139 | − 7.177 | 1.36 | 0.010 | 0.010 | 0.655937 | − 7.152 | 1.56 |
| RI | 1832 | 1791 | 1878 | ||||||||||||
| Pre-monsoon | |||||||||||||||
| Al | – | – | 0.012955 | − 11.876 | 2.01 | – | – | 0.010717 | − 12.802 | 1.67 | – | – | 0.027351 | − 11.787 | 8.42 |
| As | 1.453 | 14.533 | 54.47276 | 0.161 | 1.27 | 1.227 | 12.267 | 71.98748 | − 0.084 | 1.21 | 1.153 | 11.533 | 85.64356 | − 0.173 | 1.05 |
| Cd | 4.200 | 126.000 | 324.8376 | 2.737 | 3.21 | 2.200 | 66.000 | 266.4133 | 1.804 | 3.93 | 1.330 | 39.900 | 203.7954 | 1.078 | 3.33 |
| Cr | 0.440 | 0.880 | 14.29285 | − 1.769 | 0.95 | 0.036 | 0.071 | 1.814032 | − 5.394 | 2.41 | 0.017 | 0.034 | 1.079758 | − 6.482 | 1.80 |
| Cu | 0.122 | 0.610 | 0.792604 | − 5.942 | 3.32 | 0.045 | 0.223 | 0.453678 | − 7.394 | 2.90 | 0.045 | 0.224 | 0.576634 | − 7.387 | 2.41 |
| Fe | – | – | 1 | − 5.607 | 43.25 | – | – | 1 | − 6.253 | 2505.88 | – | – | 1 | − 6.593 | 1000.00 |
| Hg | 61.200 | 2448.000 | 1242.504 | 4.672 | 0.88 | 33.720 | 1348.800 | 1071.89 | 3.812 | 0.88 | 43.200 | 1728.000 | 1737.624 | 4.17 | 0.82 |
| Pb | 0.453 | 2.264 | 12.87169 | − 1.92 | 3.13 | 0.036 | 0.181 | 1.60847 | − 5.568 | 2.43 | 0.025 | 0.124 | 1.399752 | − 6.108 | 2.38 |
| Se | – | – | 16.24188 | − 1.585 | 1.25 | – | – | 9.573783 | − 2.994 | 2.29 | – | – | 30.28538 | − 1.672 | 2.00 |
| Zn | 0.052 | 0.052 | 1.791528 | − 4.765 | 3.03 | 0.010 | 0.010 | 0.554844 | − 7.103 | 2.31 | 0.006 | 0.006 | 0.429043 | − 7.814 | 3.16 |
| RI | 2592 | 1427 | 1779 | ||||||||||||
| Average of three seasons at three sites | |||||||||||||||
| Al | – | – | 0.01 | − 12.08 | 1.53 | – | 10.31 | 0.01 | − 13.19 | 1.26 | – | – | 0.02 | − 11.92 | 4.69 |
| As | 1.31 | 13.13 | 52.81 | 0.01 | 0.87 | 1.03 | 54.70 | 59.29 | − 0.35 | 0.91 | 1.08 | 10.82 | 77.04 | − 0.27 | 0.89 |
| Cd | 3.33 | 100.00 | 274.73 | 2.38 | 1.72 | 1.82 | 0.06 | 216.54 | 1.52 | 2.12 | 1.00 | 30.00 | 148.08 | 0.63 | 2.00 |
| Cr | 0.38 | 0.76 | 13.15 | − 2.00 | 0.76 | 0.03 | 0.20 | 1.60 | − 5.55 | 0.93 | 0.01 | 0.03 | 0.82 | − 6.87 | 1.10 |
| Cu | 0.11 | 0.55 | 0.77 | − 6.10 | 1.90 | 0.04 | – | 0.40 | − 7.54 | 1.74 | 0.04 | 0.21 | 0.51 | − 7.52 | 1.72 |
| Fe | – | – | 1.00 | − 5.71 | 41.20 | – | 1617.60 | 1.00 | − 6.22 | 1700.00 | – | – | 1.00 | − 6.53 | 887.39 |
| Hg | 51.87 | 2074.67 | 1126.52 | 4.42 | 0.79 | 40.44 | 0.15 | 1253.48 | 4.06 | 0.86 | 47.20 | 1888.00 | 1812.27 | 4.29 | 0.82 |
| Pb | 0.38 | 1.87 | 11.37 | − 2.21 | 2.14 | 0.03 | – | 1.32 | − 5.84 | 1.55 | 0.02 | 0.10 | 1.10 | − 6.44 | 1.78 |
| Se | – | – | 14.70 | − 1.84 | 1.00 | – | 0.01 | 7.82 | − 3.27 | 1.50 | – | – | 26.72 | − 1.81 | 1.17 |
| Zn | 0.04 | 0.04 | 1.38 | − 5.28 | 1.75 | 0.01 | 0.008 | 0.49 | − 7.27 | 1.57 | 0.01 | 0.01 | 0.49 | − 7.60 | 1.85 |
| RI | 2191 | 1683 | 1929 | ||||||||||||