Table 1. Ethylene polymerization for cocatalyst selectiona.
| Entry | Co-catalyst | Al/Ni | Activityb | M w c | M w/Mnc | T m d |
|---|---|---|---|---|---|---|
| 1 | MAO | 2000 | 7.04 | 8.66 | 2.11 | 57.11 |
| 2 | MMAO | 2000 | 3.47 | 20.69 | 1.77 | 95.14 |
| 3 | EASC | 400 | 0.33 | 13.49 | 1.55 | 55.40 |
| 4 | Et2AlCl | 600 | 4.27 | 9.02 | 3.37 | 41.18 |
Conditions: 2 μmol Ni1 and 100 mL toluene, 10 atm C2H4, 30 °C, 30 min.
106 g(PE) mol−1 (Ni) h−1.
M w: 105 g mol−1, Mw and Mw/Mn determined by GPC.
Determined by DSC.