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. 2025 Aug 19;15(36):29176–29189. doi: 10.1039/d5ra04469c

Table 5. Rate constants k and correlation coefficients R2 for the leaching of Ni at different temperatures for the chemical reaction controlled model and the diffusion through the product layer model.

Saprolite laterite Limonite laterite
Diffusion through the product layer Chemical reaction Diffusion through the product layer Chemical reaction
1 − 2/3x−(1 − x)2/3 1 − (1 − x)1/3 1 − 2/3x−(1 − x)2/3 1 − (1 − x)1/3
k R 2 k R 2 k R 2 k R 2
100 0.000876 0.99036 0.003119 0.95677 0.000812 0.99038 0.097538 0.95461
120 0.001035 0.99684 0.003451 0.96923 0.000959 0.99694 0.006491 0.96684
140 0.001225 0.99632 0.003838 0.98212 0.001134 0.99661 0.006858 0.98007
160 0.001494 0.9903 0.004378 0.98267 0.001361 0.9926 0.00725 0.98002
180 0.001851 0.99607 0.005108 0.98953 0.001751 0.99652 0.00775 0.97907