Table 1. Photophysical data of the free guests (1 and 2) and their complexes with host molecules in a buffer solution (pH 4.7).
| λ abs (nm) | λ em (nm) | Lifetime (ns) | Quantum yield | Enhancement factor | K a (M−1) | |
|---|---|---|---|---|---|---|
| 1 | 257 max, 309 sh, 381 sh | 575 | 22 | 0.014 ± 0.002 | — | — |
| Q[8]·1 | — | 552 | 279 | — | 6 times | |
| Q[10]·1 | 260 max, 312 sh, 388 sh | 540 | 499 | 0.142 ± 0.016 | 40 times | 1.02 × 106 |
| 93 | ||||||
| 2 | 254 max, 324 sh, 381 sh | 578 | 13 | 0.023 ± 0.004 | — | — |
| Q[8]·2 | — | 557 | 27 | — | 2 times | — |
| Q[10]·2 | 261 max, 325 sh, 388 sh | 553 | 309 | 0.060 ± 0.002 | 20 times | 2.31 × 105 |
| 98 |