Table 1. Cerium–carbon distance (Å), including literature values and present systems.
| Bond type | Bond distance (Å) | Reference |
|---|---|---|
| CeIII–Ccyanide | 2.596(15)–2.736(17) | 31 |
| CeIII–Calkynyl | 2.549(3)–2.71(2) | 32 |
| CeIII–Calkynyl | 2.652(9) | 33 |
| CeIV–Ccarbene | 2.652(7)–2.705(2) | 25 |
| CeIV–Caryl | 2.571(7)–2.5806(19) | 2 |
| CeIV–Caryl | 2.539(3) | 26 |
| CeIV–Calkyl | 2.515(4) | 26 |
| CeIV–Calkyl | 2.508(2)–2.562(2) | 27 |
| CeIV–Calkynyl | 2.478(3)–2.523(10) | 26 |
| CeIV–Calkynyl | 2.513(5) | 1-CePh |
| CeIV–Calkynyl | 2.501(3) | 1-CeTMS |
| CeIV–Cheter-atom supported multiple bond | 2.385(2)–2.441(5) | 14 |