. 2025 Aug 27;64(35):17935–17945. doi: 10.1021/acs.inorgchem.5c02940

3. Electrochemical Parameters of V ₆ O ₇ ⁰, V ₆ O ₆ Cl ^–, V ₆ O ₆ SCN ^–, and V ₆ O ₆ ⁰ in Dichloromethane.

redox couple	V ₆ O ₇ ⁰ E _1/2 (vs Fc^+/0)	redox couple	V ₆ O ₆ ⁰ E _1/2 (vs Fc^+/0)	V ₆ O ₆ Cl ^– E _1/2 (vs Fc^+/0)	V ₆ O ₆ SCN ^– E _1/2 (vs Fc^+/0)
[V^IV ₆]/[V^IV ₅V^V]	–1.16	[V^IIIV^IV ₅]/[V^IIIV^IV ₄V^V]	–0.85	–1.02	–0.99
[V^IV ₅V^V]/[V^IV ₄V^V ₂]	–0.62	[V^IIIV^IV ₄V^V]/[V^IIIV^IV ₃V^V ₂]	–0.21	–0.47	–0.43
[V^IV ₄V^V ₂]/[V^IV ₃V^V ₃]	+0.07	[V^IIIV^IV ₃V^V ₂]/[V^IIIV^IV ₂V^V ₃]	+0.46	+0.23	+0.29
[V^IV ₃V^V ₃]/[V^IV ₂V^V ₄]	+0.75	[V^IIIV^IV ₂V^V ₃]/[V^IIIV^IVV^V ₄]	+1.11	+0.92	+0.96

3. Electrochemical Parameters of V 6 O 7 0 , V 6 O 6 Cl – , V 6 O 6 SCN – , and V 6 O 6 0 in Dichloromethane.