9. Overview of Crystal Structures of Compounds with Composition M[E VF6] (M = Li, Na, K, Rb, and Cs; E V = P, As, Sb, Bi, Pa, U, Np, and Pu).
| M | E V | structure type | space group (No.) | a/Å | b/Å | c/Å | V/Å3 | Lit. |
|---|---|---|---|---|---|---|---|---|
| Li | P | LiSbF6 | R3̅ (148) | 4.932 | a | 12.658 | 266.65 | |
| As | 5.016 | a | 13.028 | 283.87 | ||||
| Sb | 5.18 | a | 13.60 | 316.03 | ||||
| Bi | 5.181 | a | 13.99 | 325.22 | ||||
| U | 5.1902(7) | a | 14.265(3) | 332.78(1) | this work | |||
| Na | P | NaSbF6 | Fm3̅m (225) | 7.6140 | a | a | 441.41 | |
| As | LiSbF6 | R3̅ (148) | 5.3375 | a | 13.9645 | 344.53 | ||
| As | NaSbF6 | Fm3̅m (225) | 7.8608 | a | a | 485.74 | ||
| Sb | NaSbF6 | Fm3̅m (225) | 8.203 | a | a | 551.97 | ||
| Bi | LiSbF6 | R3̅ (148) | 5.468 | a | 15.16 | 392.54 | ||
| U | LiSbF6 | R3̅ (148) | 5.4101(8) | a | 15.746(3) | 399.12(1) | this work | |
| U | NaSbF6 | Fm3̅m (225) | 8.608 | a | a | 637.83 | ||
| Pa | ? | ? | 5.35 | a | 3.98 | 113.92 | ||
| K | P | KPF6 | Fm3̅m (225) | 7.7891 | a | a | 472.57 | |
| As | KAsF6 | R3̅ (148) | 7.348 | a | 7.274 | 340.13 | ||
| Sb | KNbF6 | P4̅2m (111) | 5.16 | a | 10.07 | 268.12 | , | |
| Sb | KSbF6 | Ia3̅ (206) | 10.15 | a | a | 1045.68 | ||
| Bi | KNbF6 | P4̅c2 (116) | 5.248 | a | 10.07 | 277.34 | ||
| Bi | KSbF6 | Ia3̅ (206) | 10.34 | a | a | 1105.51 | ||
| U | KUF6 | C2/m (12) | 11.4415(2) | 8.0345(1) | 5.5655(1) | 511.62(4) | this work | |
| Pa | ? | ? | 5.64 | 11.54 | 7.98 | 519.38 | ||
| Rb | P | KPF6 | Fm3̅m (225) | 7.887 | a | a | 490.61 | |
| As | KAsF6 | R3̅ (148) | 7.497 | a | 7.589 | 369.39 | ||
| As | CsPF6 | Fm3̅m (225) | 8.246 | a | a | 560.7 | ||
| Sb | KAsF6 | R3̅ (148) | 7.670 | a | 7.861 | 400.50 | ||
| Sb | Ca□B6 | Pm3̅m (221) | 5.287 | a | a | 147.8 | ||
| Bi | KAsF6 | R3̅ (148) | 7.712 | a | 7.889 | 406.34 | ||
| U | KUF6 | C2/m (12) | 11.797(2) | 8.0167(2) | 5.7272(1) | 541.64(2) | this work | |
| Pa | RbPaF6 | Cmme (67) | 8.0483 | 12.0253 | 5.8608 | 567.23 | ||
| Cs | P | KPF6 | Fm3̅m (225) | 8.197 | a | a | 550.76 | |
| As | KAsF6 | R3̅ (148) | 7.723 | a | 8.050 | 415.81 | ||
| As | CsPF6 | Fm3̅m (225) | 8.384 | a | a | 589.32 | ||
| Sb | KAsF6 | R3̅ (148) | 7.904 | a | 8.261 | 446.95 | ||
| Sb | Ca□B6 | Pm3̅m (221) | 5.474 | a | a | 164.03 | ||
| Bi | KAsF6 | R3̅ (148) | 7.930 | a | 8.274 | 450.60 | ||
| U | KAsF6 | R3̅ (148) | 8.019 | a | 8.437 | 469.9 | ||
| Pa | ? | ? | 6.14 | 12.56 | 8.06 | 621.57 | ||
| Np | KAsF6 | R3̅ (148) | 8.017 | a | 8.386 | 466.78 | ||
| Pu | ? | ? | 8.006 | a | 8.370 | 464.61 |
a
Hexagonal setting.