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Decarboxylative amination of bicyclo[1.1.1]pentanes (BCPs).a
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Performed on a 0.4 mmol scale with corresponding iodonium carboxylate (1.0 equiv.), sulfoximine (2.0 equiv), Ir[dF(Me)ppy]2(4,4′-dtbbpy)PF6 (2 mol%), Cu(acac)2 (50 mol%), BTTP (1 equiv) in 1,4-dioxane (0.33 M) in the integrated photoreactor (450 nm, 25% light intensity for 1 h); BTTP: tert-butylimino-tri(pyrrolidino)phosphorane. See Supporting Information for experimental details.
