1. Odor-Active Compounds Identified in Aroma Distillates Isolated from Different Hemp Cultivars during AEDA.

			retention index on		FD factor
no.	odorant	odor quality	FFAP	DB-5	PG071	PG072	PG073	PG074	PG075.1	PG076	ref.
1	ethyl propanoate	fruity, flue-like	943	712	64	16	64	32	128	32
2	α-pinene	pine-like	1003	930	1024	1024	1024	1024	1024	1024
3	methyl 3-methylbutanoate	fruity	1012	764	128			256	1024
4	ethyl 2-methylbutanoate	fruity	1023	847	1024	256	64	128	1024	1024
5	ethyl 3-methylbutanoate	fruity	1053	851	1024	1024	1024		1024	1024
6	3-methylbut-2-ene-1-thiol	hemp, beer	1085	816	64	32	16	256	256	1024
7	β-pinene	terpene-like	1092	978	64	32	64	8	256	1024
8	myrcene	hop-like	1151	991	1024	1024	1024	512	1024	256
9	1,8-cineole (eucalyptol)	eucalyptus-like	1165	1038	64	256	16	4	16	512
10	limonene	citrus-like	1190	1033	256	1024	16	128	16	512
11	β-phellandrene	terpene-like	1234	1035	16			4
12	unknown	mushroom	1241	1063		32		4
13	3-methylbutyl 2-methylbutanoate	fruity	1267	1100	16
14	octanal	fruity, citrus-like	1281	941		32
15	2-acetyl-1-pyrroline	popcorn-like,	1322	920	64	32	64	32
		roasty
16	4-methyl-4-sulfanylpentan-2-one	sulfury, exotic	1370	934	16	1024	256	64	256	32
17	3-methoxy-2,5-dimethylpyrazine	earthy	1414	1054	512	256	16	128
18	acetic acid	vinegar-like	1442	625	64	32	16	128	8	4
19	3-(methylsulfanyl)propanal (methional)	cooked potato	1453	899	64	256	16	16	64	64
20	3-isobutyl-2-methoxypyrazine	earthy, bell	1511	1179				32	16	128
		pepper-like
21	linalool	citrus-like, floral	1539	1103	256	256	1024	1024	256	256
22	octan-1-ol	citrus-like, green	1553	1167	256		64	128	32	32
23	β-caryophyllene	moldy	1578	1421	256	16	16	128	4	4
24	2-acetylpyrazine	popcorn	1618	1020				16	128
25	butanoic acid	sweaty	1620	816	256			128	16
26	α-humulene	hop-like	1623	1457	64	16	16	128	128	1024
27	3-methylbutanoic acid	sweaty	1662	857	16	16	64	256	512	64
28	2-methylbutanoic acid	sweaty	1662	857	16	16	64	256	512	64
29	isoborneol	moldy	1674	1167	64					64
30	α-terpineol	floral, citrus-like	1686	1194	64	256	256	128	128
31	3-sulfanylhexyl acetate	passion fruit	1713	1249	256	32		1024	1024	512
32	(2E)-undec-2-enal,	soapy, metallic	1746	1384	16	8		16	16	128
33	β-citronellol	perfume, rose-like	1762	1233		32		32	4	4
34	nerol	rose-like, flowery	1785	1230					128
35	unknown	passion fruit	1814	1056					16
36	3-sulfanylhexan-1-ol	tropical fruit,	1829	1125	64	16	16	1024	1024	64
		exotic
37	hexanoic acid	sweaty	1839	1012				16
38	2-methoxyphenol	smoky	1854	1095		32
39	(2E,4E,6Z)-nona-2,4,6-trienal	oatmeal-like, sweet	1863	1277	64	256			32
40	(E)-β-ionone	floral, violet-like	1931	1495		32		32	8
41	trans-4,5-epoxy-(2E)-dec-2-enal	metallic	2000	1378	64	32	16	8
42	4-hydroxy-2,5-dimethylfuran-3(2H)-one (furaneol)	caramel-like	2031	1067	2			128	1024	128
43	4-methylphenol (p-cresol)	phenolic, smoky	2080	1080	256	1024	32			64
44	eugenol (4-allyl-2-methoxyphenol)	clove-like, sweet	2162	1358	256	32	32	1024	64	64	,
45	3-hydroxy-4,5-dimethylfuran-2(5H)-one (sotolon)	fenugreek-like,	2179	1108	2	16	16	512	64	16
		lovage-like
46	2-methoxy-4-vinylphenol	smoky, clove-like	2194	1316		256	256	256	32	512
47	methyl anthranilate	sweet	2237	1344	64	64	8	256	256	512
48	unknown	pepper-like, musty	2256	1720	16	256		128
49	unknown	peach-like	2398	1653					16
50	indole	mothball-like	2442	1296	64	64	64	64
51	3-methyl-1H-indole (skatole)	mothball-like	2497	1390	64		64	32
52	phenylacetic acid	honey-like,	2571	1266		16	8	128	8	16
		beeswax-like

^aOdorants were numbered according to their retention indices on capillary column FFAP.

^bOdorant identified by comparison of its odor quality and intensity at the sniffing port and retention indices on capillaries DB-FFAP, DB-5 as well as mass spectra with data of reference compounds.

^cOdor quality perceived at the sniffing port.

^dFlavor dilution factor determined by AEDA on capillary FFAP.

^eNo unequivocal mass spectrum was obtained. Identification is based on the remaining criteria in footnote b.

^fCompounds were tentatively identified based on comparison with literature data (odor and retention indices).

^gCompounds were reported for the first time in Cannabis flowers.