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. 2025 Sep 24;28:100398. doi: 10.1016/j.metop.2025.100398

Table 1.

Summary of the included studies.

Author(s), Year, Country Study Design and Sample Size Study Population Characteristics Biospecimen Type and Timing Analytical Platform and Lipidomic Approach Main Outcomes and Findings
He et al. (2021), USA [2] Nested case-control study; N = 64 (44 severe preeclampsia, 20 controls) Multiethnic pregnant women in Hawaii; significant differences in gestational age, gestational diabetes, and parity; only cases had smokers or gestational diabetes Maternal plasma; collected during pregnancy (biobank-derived samples) Untargeted lipidomics using LC-MS/MS (TripleTOF 5600); LipidBlast database; WGCNA; machine learning (e.g., random forest) 11 lipid species associated with severe preeclampsia (e.g., LPC 15:0, PC 35:1e, PE 37:2); enriched pathways include insulin signaling, immune response, PL metabolism; RF model: F1 = 0.94, accuracy = 0.88
Yang et al. (2023), China [5] Case-control study; N = 40 (20 LOPE, 20 controls) Singleton pregnancies; exclusion of pre-existing conditions; significant differences in BMI, BP, neonatal weight; matched for age, parity, gestational age Placental tissue; collected immediately post-delivery (within 5 min), snap frozen Untargeted LC-MS/MS (UHPLC-Q-Exactive Orbitrap MS); XCMS + LipidBlast; WGCNA; OPLS-DA; MetaboAnalyst 226 differentially expressed lipids (94 ↑, 132 ↓); LOPE linked to increased TGs (esp. Unsaturated FAs) and decreased PC, PE, PS; key pathway: glycerophospholipid metabolism; co-expression modules correlated with SBP and BMI
Mires et al. (2024), UK [9] Observational study; maternal plasma from 98 CHD and 62 control pregnancies Mothers of children with congenital heart disease (CHD); samples collected postnatally; matched on age and BMI; exclusion of pre-existing metabolic disorders Maternal plasma; collected 6 weeks postpartum Untargeted metabolomics and lipidomics via LC-MS (positive and negative ion modes); analyzed using multivariate statistics (PCA, OPLS-DA), machine learning classifiers Distinct metabolic/lipidomic signatures differentiate CHD vs. control mothers; key lipid species include phosphatidylcholines and acylcarnitines; achieved high classification accuracy using integrated profiles
Huang et al. (2024), China [13] Case-control; N = 58 (20 controls, 19 EOPE, 19 LOPE) Pregnant women; EOPE and LOPE classified by gestational age; matched controls; exclusion criteria applied Maternal plasma samples collected during pregnancy Untargeted lipidomics using UPLC-MS/MS; multivariate analysis; WGCNA; ROC curve analysis Strong lipidomic separation between EOPE, LOPE, and controls; AUC = 1.000 (EOPE vs. control), AUC = 0.992 (LOPE vs. control); lipids linked to glycerophospholipid metabolism and correlated with fetal birth weight and urine protein
Alahakoon et al. (2020), Australia Prospective cross-sectional case-control study Pregnant women with PE, FGR, PE + FGR, and normal controls; FGR defined by elevated umbilical artery resistance and EFW <10 % Maternal and fetal serum; collected at delivery Enzymatic and immunoturbidimetric assays for TC, HDL, LDL, TG, ApoA1, ApoB Elevated maternal TG in PE; increased fetal TG in PE + FGR; significantly higher fetal ApoB in PE, FGR, PE + FGR; no group differences in TC, HDL, LDL or ApoA1
Chen et al. (2023), Singapore [1] Prospective longitudinal cohort (S-PRESTO); N = 1595 plasma samples from 976 women Healthy women from preconception to postpartum; followed through pregnancy and 3 months postpartum Plasma samples at 3 timepoints: preconception, 26–28 weeks gestation, and 3 months postpartum LC-MS/MS; quantification of 689 lipid species; analysis includes clustering, regression models, and pathway enrichment Identified dynamic lipidomic changes during pregnancy; 56 % of lipids changed over time; key lipid clusters associated with BMI, weight gain, glycemic traits; potential early markers of cardiometabolic risk
Antonic et al. (2025), Serbia [6] Prospective cohort study; N = 90 (70 high-risk controls, 20 developed late-onset preeclampsia) Pregnant women at high risk for preeclampsia; followed across 4 gestational time points Maternal serum; collected during 1st trimester, 2nd trimester, 3rd trimester, and delivery Targeted sphingolipid profiling using LC-MS/MS S1P, ceramides (C16:0, C24:0), and sphingomyelin C16:0 tracked over time; S1P significantly lower in PE group vs. controls from 2nd trimester onward; ceramides increased in high-risk group over time; sphingomyelin rose in both groups with no group difference
Rahman et al. (2021), USA Prospective nested case-control; N = 321 (107 GDM, 214 controls) Multiethnic pregnant women (NICHD Fetal Growth Studies); no preexisting diabetes; matched on site, age, race/ethnicity Maternal plasma at 10–14 and 15–26 weeks Untargeted lipidomics (420 metabolites, 328 annotated) using LC-MS; WGCNA; linear mixed models; FDR correction Lipid networks enriched in diglycerides and saturated/low-unsaturated TGs were associated with increased GDM risk; 40 lipids significantly differed at both timepoints; lipids correlated with glucose, insulin, HbA1c, C-peptide
Wang et al. (2023), USA [20] Prospective cohort study; N = 1409; 219 developed type 2 diabetes Postpartum women (within 72 h after singleton delivery) from Boston Medical Center; followed for median 11.8 years Plasma; collected at 24–72 h postpartum Untargeted lipidomics via LC-MS/MS; lipidome-wide association; adjusted regression models 33 lipids associated with GDM (16 ↓ including CE, PC plasmalogens; 17 ↑ including DAGs, TAGs); 4 lipids also predicted T2D and mediated 12 % of GDM-to-T2D progression; improved T2D prediction beyond classical risk factors
Williams et al. (2023), USA [19] Prospective cohort; N = 63 women with obesity (10 developed PE) Pregnant women with obesity; followed longitudinally by trimester; evaluated by PE status, race, fetal sex Maternal plasma; collected in each trimester Targeted lipidomics and standard lipid panels; LC-MS/MS; stratified by trimester, race, and fetal sex Elevated plasmalogens, PE, and FFA species in 3rd trimester in women with PE; race and pregnancy stage significantly influenced lipidomic profiles; standard lipids showed few differences
Song et al. (2023), USA/Singapore Prospective longitudinal cohort; N = 321 pregnant women from NICHD Fetal Growth Study Multiethnic cohort; healthy singleton pregnancies; followed through 4 visits during pregnancy Maternal plasma; collected at 10–14, 15–26, 23–31, and 33–39 weeks Untargeted lipidomics via LC-MS/MS; WGCNA and consensus network analysis; FDR-controlled linear mixed models TGs positively associated with birthweight, head circumference; CEs, PCs, SMs, PEs, and LPCs inversely associated with multiple neonatal size measures; distinct lipid modules linked to fetal growth parameters across gestation
Enthoven et al. (2023), USA [15] Within-subject longitudinal study; N = 47 pregnant women Healthy women aged 18–50; paired samples during pregnancy and ∼3 months postpartum Maternal plasma; 25–28 weeks gestation and ∼3 months postpartum UPLC-MS/MS metabolomics for 43 sphingolipids; followed by targeted quantitative LC-MS/MS analysis 35 of 43 sphingolipids differed significantly between pregnancy and postpartum; 32 higher during pregnancy, especially sphingomyelins and ceramides; consistent with adaptations in maternal lipid metabolism during gestation
Traila et al. (2025), Romania Mixed longitudinal and cross-sectional study; N = 107 (65 pregnant women, 42 postpartum controls) Healthy women; pregnant group sampled across three trimesters; postpartum group used as reference Plasma; collected at 6–14 weeks, 14–22 weeks, >24 weeks gestation and postpartum UHPLC-QTOF-ESI+-MS lipidomics; multivariate analysis (PLS-DA), VIP scores, and clustering Significant lipidomic shifts across pregnancy; 16 lipids showed consistent changes, including PCs, SMs, ceramides, and glycerolipids; lipids discriminated pregnant vs. postpartum states; potential biomarkers for gestational progression
Aung et al. (2021), USA [12] Nested case-control from a birth cohort; N = 100 (50 preterm, 50 term) Diverse pregnant women from San Francisco; samples matched by gestational age at collection Maternal plasma at 15–20 weeks gestation Untargeted lipidomics via LC-MS/MS; 387 lipids quantified 38 lipid species significantly associated with preterm birth; lower levels of PCs, PEs, and SMs observed in preterm group; lipidome may aid early risk stratification for preterm delivery
Mustaniemi et al. (2023), Finland [14] Nested case–control study within FinnGeDi; N = 264 (132 GDM, 132 controls) Pregnant women from the general population in Finland; matched for age and gestational age Maternal serum; collected at ∼13 weeks gestation (early pregnancy) Targeted lipidomics via LC-MS/MS; ceramides and traditional lipids; 4 ceramide species and Cer(d18:1/18:0)/Cer(d18:1/16:0) ratio analyzed Higher levels of Cer(d18:1/18:0), Cer(d18:1/24:1), and the Cer(18:0/16:0) ratio in women who developed GDM; predictive potential of ceramides independent of BMI; supports use of ceramides as early biomarkers for GDM risk
Miranda et al. (2018), Spain [17] Prospective cohort study; N = 80 (28 AGA, 25 SGA, 27 FGR) Pregnant women at term; classified as AGA (controls), SGA, or FGR (cases); recruited in Barcelona Maternal plasma and umbilical cord plasma; collected at delivery (non-fasting) 1H NMR spectroscopy; Liposcale for lipoprotein profiling and phosphatidylcholines; Dolphin for low-molecular-weight metabolites Lower maternal IDL, VLDL, HDL cholesterol/triglycerides in SGA/FGR vs. AGA; higher fetal VLDL/IDL cholesterol and triglycerides in FGR; altered phosphatidylcholines and glycoproteins; supports disrupted lipid metabolism in fetal growth restriction and potential long-term metabolic risks

AGA – Appropriate for Gestational Age; ApoA1 – Apolipoprotein A1; ApoB – Apolipoprotein B; AUC – Area Under the Curve; BMI – Body Mass Index; BP – Blood Pressure; CE – Cholesteryl Ester; CHD – Congenital Heart Disease; DAG – Diacylglycerol; EOPE – Early-Onset Preeclampsia; EFW – Estimated Fetal Weight; FA – Fatty Acid; FDR – False Discovery Rate; FFA – Free Fatty Acid; FGR – Fetal Growth Restriction; GDM – Gestational Diabetes Mellitus; HDL – High-Density Lipoprotein; IDL – Intermediate-Density Lipoprotein; LC-MS – Liquid Chromatography-Mass Spectrometry; LC-MS/MS – Liquid Chromatography-Tandem Mass Spectrometry; LDL – Low-Density Lipoprotein; LOPE – Late-Onset Preeclampsia; LPC – Lysophosphatidylcholine; MetaboAnalyst – Metabolomics Analysis Platform; NICHD – National Institute of Child Health and Human Development; NMR – Nuclear Magnetic Resonance; OPLS-DA – Orthogonal Partial Least Squares Discriminant Analysis; PCA – Principal Component Analysis; PC – Phosphatidylcholine; PE – Preeclampsia/Phosphatidylethanolamine (context-dependent); PL – Phospholipid; PLS-DA – Partial Least Squares Discriminant Analysis; PS – Phosphatidylserine; RF – Random Forest; ROC – Receiver Operating Characteristic; S1P – Sphingosine-1-Phosphate; SBP – Systolic Blood Pressure; SGA – Small for Gestational Age; SM – Sphingomyelin; S-PRESTO – Singapore Preconception Study of Long-Term Maternal and Child Outcomes; TAG – Triacylglycerol; TC – Total Cholesterol; TG – Triglyceride; T2D – Type 2 Diabetes; UHPLC – Ultra High Performance Liquid Chromatography; UHPLC-Q-Exactive Orbitrap MS – Ultra High Performance Liquid Chromatography Quadrupole Exactive Orbitrap Mass Spectrometry; UHPLC-QTOF-ESI+-MS – Ultra High Performance Liquid Chromatography Quadrupole Time of Flight Electrospray Ionization Mass Spectrometry; VIP – Variable Importance in Projection; VLDL – Very-Low-Density Lipoprotein; WGCNA – Weighted Gene Co-expression Network Analysis.