TABLE 1.
NMR chemical shifts for bacilysocin in MeOH-d4
| Moiety | Carbon no. | δH | δC (ppm) |
|---|---|---|---|
| Acyl | 13′″ | 0.85 (3H,d) | 19.63 |
| 14″ | 0.87 (3H, t) | 11.74 | |
| 13″ | 1.15, 1.3 (2H, m) | 30.72 | |
| 12″ | 1.3 (H, m) | 35.70 | |
| 11″ | 1.1, 1.3 (2H, m) | 37.80 | |
| 4″–10″ | 1.2–1.4 (14H, m) | 28.20, 30.23, 30.43, 30.59, 30.62, 30.78, 31.11 | |
| 3″ | 1.60 (2H, m) | 25.99 | |
| 2″ | 2.35 (2H, dt) | 34.93 | |
| 1″ | 175.40 | ||
| Glycerate | 3′ | 3.55, 3.61 (1H, dd) | 63.87 |
| 2′ | 3.76 (1H, m) | 72.66 | |
| 1′ | 3.89 (4H, m) | 67.58 | |
| Glycerol | 3 | 3.92 (1H, m) | 67.61 |
| 2 | 3.96 (1H, m) | 69.93 | |
| 1 | 4.10, 4.17 (1H, dd) | 66.27 |