2. Structural Parameters for the Ni­(Mn)–O and Ni­(Mn)–TM^1st Two-Body Distributions Obtained from the EXAFS Data Analysis of the Ni and Mn K-edge MCR Analysis-Derived Pure Spectral Components .

		N	R (Å)	σ2 (Å2)	β
Ni K-edge
Pure component 1	Ni–O	5.5(5)	2.04(2)	0.002(2)	0.0(1)
	Ni–TMfirst	4.0(6)	2.90(3)	0.005(3)	0.0(2)
Pure component 2	Ni–O	5.5(5)	1.89(2)	0.001(3)	0.7(1)
	Ni–TMfirst	4.3(6)	2.87(3)	0.003(3)	0.7(2)
Mn K-edge
Pure component 1	Mn–O	6.0(5)	1.90(2)	0.005(2)	0.1(1)
	Mn–TMfirst	2.0(6)	2.87(3)	0.005(3)	0.7(2)
Pure component 2	Mn–O	6.0(5)	1.90(2)	0.003(2)	0.1(1)
	Mn–TMfirst	5.0(6)	2.89(3)	0.008(3)	0.7(2)

^a N is the coordination number, R the average distance, σ² the Debye–Waller factor, and β the asymmetry index. Standard deviation in parentheses.