Table 4. Pseudo-first-order reaction-rate constants and relative rates for each compound in the model SN2 reaction at 298 K.
| Compound | k (min−1) | k (relative to pyridine) |
|---|---|---|
| Pyridine | 0.000259 | 1.0 |
| DMAP | 0.00171 | 6.6 |
| 3 | 0.00488 | 18.9 |
| 4 | 0.00254 | 9.8 |
| 5 | 0.00698 | 26.9 |
| 6 | 0.00237 | 9.1 |
| 7 | 0.00661 | 25.5 |
| 8 | 0.00420 | 16.2 |
| 9 | 0.00727 | 28.1 |
| 10 | 0.00502 | 19.4 |