Table 3.

Identification of the blood-entering phytochemical components of the BYJHD

NO.	Compound Identification	Rt (min)	Formula	Adducts	Measured value (m/z)
01	D-mannitol	0.766	C6H14O6	[M-H]−	181.072
02	Lapachol	0.894	C15H20O9	[M + FA-H]−	389.110
03	2-O-alpha-D-Glucopyranosyl-L-ascorbic acid	0.875	C12H18O11	[M-H]−	337.078
04	O-Acetylethanolamine	1.087	C4H9NO2	[M-H]−	102.056
05	trans-5-Hydroxyferulic acid	3.041	C10H10O5	[M + FA-H]−	255.051
06	Ethyl salicylate	3.846	C9H10O3	[M + FA-H]−	211.061
07	Bemegrid	3.989	C8H13NO2	[M + FA-H]−	200.093
08	Myxopyroside	4.094	C18H26O13	[M-H]−	449.131
09	10-Hydroxyoleoside-11-methyl ester	4.480	C17H24O12	[M-H]−	419.120
10	trans-Fertaric acid	4.986	C14H14O9	[M-H]−	325.057
11	Cyclo(D-Val-L-Pro)	5.305	C10H16N2O2	[M + FA-H]−	241.120
12	Urospermal	5.939	C15H18O5	[M-H]−	277.109
13	Cuspidiol	6.092	C14H20O3	[M + FA-H]−	281.140
14	rosmarinic acid	6.391	C18H16O8	[M-H]−	359.078
15	4-Methoxysalicylaldehyde	6.391	C8H8O3	[M-H2O-H]−	133.030
16	2’,5,6’,7-Tetraacetoxyflavanone	6.932	C23H20O10	[M + FA-H]−	501.104
17	Hexylitaconic acid	7.157	C11H18O4	[M-H]−	213.113
18	Oroxylin A-7-O-Beta-D-glucuronide	7.157	C22H20O11	[M-H]−	459.094
19	p-Hydroxy-5,6-dehydrokawain	7.237	C14H12O4	[M + FA-H]−	289.072
20	Monodictyxanthone	8.774	C15H10O5	[M-H2O-H]−	251.035
21	Epoxymicheliolide	9.209	C15H20O4	[M-H2O-H]−	245.119
22	Tetramethylcurcumin	10.137	C25H28O6	[M-H]−	423.182
23	Syringic acid	4.099	C9H10O5	[M + H]+	199.060
24	Oxysophocarpine	4.378	C15H22N2O2	[M + H]+	263.175
25	3-n-Butylphathlide	5.071	C12H14O2	[M + H-H2O]+	173.096
26	Flavinantine	5.700	C19H21NO4	[M + H-H2O]+	310.143
27	yibeinoside A	5.807	C33H53NO7	[M + H]+	576.389
28	Hispidulin 7-glucuronide	6.315	C22H20O12	[M + H]+	477.102
29	Skimmin	6.341	C15H16O8	[M + H]+	325.091
30	6-Dehydropetasol	6.620	C15H20O2	[M + H-H2O]+	215.143
31	Marsdenoside F	6.800	C39H60O14	[M + H]+	753.405
32	Alpha-Hederin	6.971	C41H66O12	[M + H]+	751.462
33	9,17-Octadecadiene-12,14-diyne-1,11,16-triol	7.194	C18H26O3	[M + NH4]+	308.221
34	Medicarpin	7.272	C16H14O4	[M + H]+	271.096
35	3-O-Methylquercetin	7.312	C16H12O7	[M + H]+	317.065
36	Citropten	8.940	C11H10O4	[M + H]+	207.065
37	Nobiletin	9.355	C21H22O8	[M + H]+	403.138
38	Nitogenin	10.294	C27H42O3	[M + H]+	415.320