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. 2025 Sep 18;4(1):37–49. doi: 10.1021/prechem.5c00083

2. Evaluation of Various Catalysts in the N-Alkylation Reaction of BIT to Prepare BBIT .

3.2.

Entry Catalysts Conversion (%) Selectivity (%) Yield (%) Standard deviation
1 None 15.89 59.96 9.53 0.65
2 Al2O3 3.97 35.27 1.40 2.03
3 MgO 26.97 74.39 20.06 1.06
4 NaOH 70.10 48.36 33.90 2.56
5 Cs/Al2O3 11.57 36.10 5.13 3.11
6 Mg/LTA 40.15 60.19 25.14 2.16
7 K/LTA 51.69 64.34 36.42 1.96
8 5%Cs/LTA 69..48 71.17 49.45 2.03
9 Mg4Al1-LDH 62.87 18.71 11.76 2.33
10 Mg4Al1O-600 61.66 69.42 42.81 1.89
a

Reaction conditions: BIT 0.0033 mol, BrBu 0.0066 mol, air, 100 °C, 20 h.