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. 2026 Jan 21;11(4):5947–5958. doi: 10.1021/acsomega.5c10186

3. Solvent Effect on FADH Using Bimetallic Ru Complexes 6–7 .

entry complex solvent yield (%) time (min) TOF20 (h–1) TOF50 (h–1)
1 6 --- 93 53 6036 2683
2 6 DMF 93 60 3011 1593
3 6 dioxane 93 105 3456 1463
4 6 toluene 93 60 2727 1986
5 7 --- 93 74 4479 1363
6 7 DMF 86 85 3591 983
7 7 dioxane 71 52 4761 3000
8 7 toluene 86 102 4285 1913
a

Reactions conducted in different solvents (0.5 mL) using FA/Cat = 1000 and Et3N/FA = 75 mol % at 90 °C.

b

TOF20 calculated at 20% of yield.

c

TOF50 calculated at 50% of yield.