Table I.
WT | cPGM29 | cPGM44 | cPGM66 | WT | pPGM5 | pPGM9 | pPGM60 | WT | AGP-85 | AGP-93 | |
---|---|---|---|---|---|---|---|---|---|---|---|
Ala | 1.00 ± 0.07 | 0.57 ± 0.11 | 0.51 ± 0.11 | 1.48 ± 0.06 | 1.00 ± 0.13 | 0.26 ± 0.04 | 0.40 ± 0.07 | 0.22 ± 0.05 | 1.00 ± 0.19 | 0.32 ± 0.04 | 0.16 ± 0.03 |
Arg | 1.00 ± 0.08 | 0.87 ± 0.18 | 0.74 ± 0.17 | 2.21 ± 0.14 | 1.00 ± 0.07 | 0.60 ± 0.05 | 0.88 ± 0.24 | 0.58 ± 0.13 | 1.00 ± 0.18 | 0.74 ± 0.05 | 0.47 ± 0.08 |
Asn | 1.00 ± 0.18 | 0.87 ± 0.15 | 0.84 ± 0.17 | 0.65 ± 0.03 | 1.00 ± 0.15 | 0.57 ± 0.16 | 0.65 ± 0.19 | 0.27 ± 0.08 | 1.00 ± 0.24 | 0.61 ± 0.09 | 0.40 ± 0.12 |
Asp | 1.00 ± 0.04 | 0.92 ± 0.06 | 0.88 ± 0.05 | 1.15 ± 0.05 | 1.00 ± 0.12 | 0.62 ± 0.09 | 0.53 ± 0.06 | 0.55 ± 0.10 | 1.00 ± 0.09 | 0.57 ± 0.06 | 0.41 ± 0.04 |
β-Ala | 1.00 ± 0.13 | 0.66 ± 0.10 | 0.93 ± 0.15 | 0.99 ± 0.11 | 1.00 ± 0.16 | 0.42 ± 0.06 | 0.40 ± 0.05 | 0.29 ± 0.05 | 1.00 ± 0.18 | 0.58 ± 0.07 | 0.55 ± 0.15 |
Cys | n.d. | n.d. | n.d. | n.d. | 1.00 ± 0.05 | 0.75 ± 0.08 | n.d. | n.d. | n.d. | n.d. | n.d. |
GABA | 1.00 ± 0.04 | 0.84 ± 0.07 | 0.74 ± 0.09 | 0.41 ± 0.03 | 1.00 ± 0.13 | 0.65 ± 0.09 | 0.63 ± 0.06 | 0.83 ± 0.08 | 1.00 ± 0.13 | 0.82 ± 0.10 | 0.79 ± 0.18 |
Glu | 1.00 ± 0.03 | 1.04 ± 0.06 | 0.95 ± 0.05 | 1.12 ± 0.04 | 1.00 ± 0.14 | 0.29 ± 0.11 | 0.54 ± 0.04 | 0.61 ± 0.12 | 1.00 ± 0.08 | 1.06 ± 0.11 | 0.75 ± 0.10 |
Gln | 1.00 ± 0.22 | 1.02 ± 0.23 | 0.98 ± 0.20 | 1.20 ± 0.21 | 1.00 ± 0.11 | 0.54 ± 0.05 | 1.00 ± 0.38 | 0.51 ± 0.11 | 1.00 ± 0.09 | 0.84 ± 0.07 | 0.63 ± 0.19 |
Gly | 1.00 ± 0.11 | 0.83 ± 0.13 | 0.64 ± 0.06 | 0.97 ± 0.08 | 1.00 ± 0.08 | 0.94 ± 0.12 | 0.63 ± 0.08 | 0.52 ± 0.09 | 1.00 ± 0.06 | 0.98 ± 0.09 | 0.85 ± 0.17 |
His | n.d. | n.d. | n.d. | n.d. | n.d. | n.d. | n.d. | n.d. | n.d. | n.d. | n.d. |
Homo-Ser | 1.00 ± 0.09 | 1.24 ± 0.24 | 1.27 ± 0.05 | 1.51 ± 0.17 | 1.00 ± 0.17 | 0.55 ± 0.04 | 1.11 ± 0.17 | 1.07 ± 0.17 | 1.00 ± 0.06 | 1.22 ± 0.09 | 1.11 ± 0.10 |
Ile | 1.00 ± 0.08 | 0.81 ± 0.09 | 0.68 ± 0.12 | 1.66 ± 0.11 | 1.00 ± 0.31 | 0.30 ± 0.03 | 1.06 ± 0.26 | 0.65 ± 0.12 | 1.00 ± 0.14 | 1.02 ± 0.09 | 0.62 ± 0.08 |
Leu | 1.00 ± 0.19 | 0.68 ± 0.15 | 0.65 ± 0.21 | 3.07 ± 0.50 | 1.00 ± 0.13 | 0.39 ± 0.06 | 1.17 ± 0.37 | 0.49 ± 0.13 | 1.00 ± 0.21 | 0.98 ± 0.15 | 0.49 ± 0.06 |
Lys | 1.00 ± 0.08 | 0.60 ± 0.07 | 0.49 ± 0.14 | 2.53 ± 0.19 | 1.00 ± 0.11 | 0.67 ± 0.03 | 1.04 ± 0.44 | 0.41 ± 0.12 | 1.00 ± 0.22 | 0.52 ± 0.04 | 0.26 ± 0.03 |
Met | 1.00 ± 0.04 | 0.76 ± 0.07 | 0.49 ± 0.12 | 1.11 ± 0.05 | 1.00 ± 0.13 | 0.56 ± 0.05 | 0.92 ± 0.18 | 0.67 ± 0.14 | 1.00 ± 0.14 | 0.72 ± 0.08 | 0.49 ± 0.10 |
Orn | 1.00 ± 0.17 | 0.76 ± 0.14 | 0.87 ± 0.23 | 1.67 ± 0.20 | 1.00 ± 0.11 | 0.45 ± 0.10 | 1.10 ± 0.30 | 0.63 ± 0.12 | 1.00 ± 0.18 | 1.01 ± 0.15 | 0.77 ± 0.14 |
5-Oxy-Pro | 1.00 ± 0.14 | 0.74 ± 0.15 | 0.97 ± 0.05 | 0.99 ± 0.13 | 1.00 ± 0.13 | 0.35 ± 0.04 | 1.07 ± 0.37 | 0.46 ± 0.14 | 1.00 ± 0.11 | 0.82 ± 0.08 | 0.64 ± 0.17 |
Phe | 1.00 ± 0.06 | 0.51 ± 0.08 | 0.36 ± 0.11 | 1.23 ± 0.05 | 1.00 ± 0.16 | 0.67 ± 0.23 | 0.83 ± 0.23 | 0.34 ± 0.08 | 1.00 ± 0.14 | 0.46 ± 0.09 | 0.18 ± 0.02 |
Pro | 1.00 ± 0.09 | 1.33 ± 0.29 | 0.51 ± 0.12 | 2.41 ± 0.52 | 1.00 ± 0.12 | 0.53 ± 0.02 | 0.45 ± 0.09 | 0.38 ± 0.11 | 1.00 ± 0.05 | 1.24 ± 0.11 | 0.79 ± 0.14 |
Ser | 1.00 ± 0.10 | 0.83 ± 0.15 | 0.57 ± 0.07 | 1.44 ± 0.08 | 1.00 ± 0.26 | 0.52 ± 0.02 | 0.62 ± 0.09 | 0.49 ± 0.10 | 1.00 ± 0.14 | 0.77 ± 0.08 | 0.55 ± 0.11 |
Thr | 1.00 ± 0.08 | 0.82 ± 0.13 | 0.64 ± 0.08 | 1.22 ± 0.07 | 1.00 ± 0.11 | 0.18 ± 0.02 | 0.68 ± 0.12 | 0.56 ± 0.11 | 1.00 ± 0.14 | 1.04 ± 0.11 | 0.76 ± 0.15 |
Trp | 1.00 ± 0.17 | 0.48 ± 0.14 | 0.22 ± 0.09 | 1.46 ± 0.27 | 1.00 ± 0.12 | 0.27 ± 0.03 | 1.40 ± 0.64 | 0.19 ± 0.06 | 1.00 ± 0.33 | 0.37 ± 0.08 | 0.14 ± 0.02 |
Tyr | 1.00 ± 0.08 | 0.48 ± 0.11 | 0.28 ± 0.12 | 1.37 ± 0.07 | 1.00 ± 0.12 | 0.70 ± 0.05 | 1.23 ± 0.53 | 0.30 ± 0.10 | 1.00 ± 0.30 | 0.43 ± 0.07 | 0.08 ± 0.01 |
Val | 1.00 ± 0.04 | 0.93 ± 0.05 | 0.96 ± 0.05 | 1.19 ± 0.02 | 1.00 ± 0.11 | 0.56 ± 0.09 | 1.00 ± 0.19 | 0.86 ± 0.16 | 1.00 ± 0.06 | 1.22 ± 0.07 | 0.92 ± 0.12 |
α-Ketogluterate | 1.00 ± 0.07 | 1.89 ± 0.23 | 1.79 ± 0.36 | 0.75 ± 0.12 | n.d. | n.d. | n.d. | n.d. | n.d. | n.d. | n.d. |
Ascorbate | 1.00 ± 0.25 | 0.48 ± 0.15 | 0.53 ± 0.22 | 1.09 ± 0.37 | 1.00 ± 0.17 | 0.86 ± 0.07 | 0.67 ± 0.20 | 0.51 ± 0.10 | 1.00 ± 0.02 | 0.93 ± 0.08 | 0.88 ± 0.09 |
Citrate | 1.00 ± 0.15 | 1.04 ± 0.15 | 1.09 ± 0.07 | 1.33 ± 0.03 | 1.00 ± 0.31 | 0.75 ± 0.05 | 0.74 ± 0.12 | 0.76 ± 0.08 | 1.00 ± 0.18 | 0.78 ± 0.03 | 0.44 ± 0.07 |
Fumarate | 1.00 ± 0.19 | 2.22 ± 0.70 | 0.85 ± 0.11 | 0.57 ± 0.07 | 1.00 ± 0.14 | 0.80 ± 0.06 | 0.69 ± 0.05 | 0.84 ± 0.08 | 1.00 ± 0.08 | 1.10 ± 0.07 | 1.01 ± 0.05 |
Glycerate | 1.00 ± 0.04 | 0.97 ± 0.20 | 0.82 ± 0.07 | 0.98 ± 0.05 | 1.00 ± 0.13 | 0.58 ± 0.04 | 0.82 ± 0.16 | 0.82 ± 0.08 | n.d. | n.d. | n.d. |
Isocitrate | 1.00 ± 0.03 | 0.56 ± 0.04 | 0.39 ± 0.05 | 3.15 ± 1.80 | 1.00 ± 0.13 | 1.13 ± 0.14 | 0.72 ± 0.17 | 0.41 ± 0.09 | 1.00 ± 0.12 | 0.60 ± 0.07 | 0.52 ± 0.07 |
Malate | 1.00 ± 0.04 | 2.14 ± 0.17 | 2.53 ± 0.36 | 1.33 ± 0.26 | 1.00 ± 0.11 | 0.58 ± 0.11 | 1.00 ± 0.15 | 1.88 ± 0.18 | 1.00 ± 0.13 | 1.26 ± 0.09 | 1.33 ± 0.13 |
Oxalate | n.d. | n.d. | n.d. | n.d. | 1.00 ± 0.22 | 1.13 ± 0.11 | 0.23 ± 0.05 | 0.37 ± 0.10 | 1.00 ± 0.28 | 0.29 ± 0.02 | 0.26 ± 0.01 |
Quinate | 1.00 ± 0.37 | 1.99 ± 0.49 | 1.89 ± 0.50 | 0.77 ± 0.16 | 1.00 ± 0.26 | 0.58 ± 0.04 | 0.63 ± 0.11 | 0.63 ± 0.17 | 1.00 ± 0.04 | 0.70 ± 0.07 | 0.75 ± 0.10 |
Shikimate | 1.00 ± 0.06 | 0.89 ± 0.11 | 0.88 ± 0.04 | 0.61 ± 0.06 | 1.00 ± 0.17 | 0.79 ± 0.06 | 0.40 ± 0.07 | 0.47 ± 0.06 | 1.00 ± 0.09 | 0.41 ± 0.02 | 0.29 ± 0.02 |
Succinate | 1.00 ± 0.17 | 0.93 ± 0.25 | 1.44 ± 0.36 | 1.09 ± 0.17 | 1.00 ± 0.18 | 0.44 ± 0.04 | 0.46 ± 0.06 | 0.37 ± 0.02 | 1.00 ± 0.25 | 0.35 ± 0.03 | 0.28 ± 0.02 |
Threonate | 1.00 ± 0.13 | 0.64 ± 0.16 | 0.57 ± 0.06 | 0.52 ± 0.11 | 1.00 ± 0.29 | 0.42 ± 0.06 | n.d. | n.d. | n.d. | n.d. | n.d. |
Fru | 1.00 ± 0.19 | 2.12 ± 0.66 | 23.35 ± 12.51 | 1.82 ± 0.32 | 1.00 ± 0.51 | 0.38 ± 0.04 | 0.35 ± 0.04 | 3.28 ± 2.14 | 1.00 ± 0.17 | 5.84 ± 3.37 | 10.52 ± 6.15 |
Gal | 1.00 ± 0.07 | 1.39 ± 0.24 | 1.01 ± 0.16 | 0.94 ± 0.10 | 1.00 ± 0.37 | 1.15 ± 0.21 | 0.71 ± 0.07 | 1.40 ± 0.34 | n.d. | 192.50 ± 26.22 | 282.17 ± 41.34 |
Glc | 1.00 ± 0.26 | 2.30 ± 0.59 | 4.46 ± 0.58 | 1.34 ± 0.30 | 1.00 ± 0.35 | 1.02 ± 0.31 | 1.79 ± 0.40 | 2.72 ± 0.37 | 1.00 ± 0.18 | 1.18 ± 0.21 | 1.18 ± 0.14 |
Inositol | 1.00 ± 0.15 | 1.29 ± 0.31 | 0.88 ± 0.05 | 0.51 ± 0.02 | 1.00 ± 0.24 | 0.47 ± 0.04 | 0.52 ± 0.05 | 0.40 ± 0.06 | 1.00 ± 0.06 | 0.58 ± 0.03 | 0.88 ± 0.05 |
Mannitol | 1.00 ± 0.04 | 1.12 ± 0.14 | 1.81 ± 0.37 | 0.43 ± 0.04 | 1.00 ± 0.08 | 0.68 ± 0.02 | 0.52 ± 0.04 | 1.45 ± 0.13 | 1.00 ± 0.12 | 1.97 ± 0.18 | 3.07 ± 0.52 |
Man | 1.00 ± 0.05 | 1.43 ± 0.19 | 1.44 ± 0.18 | 1.06 ± 0.16 | 1.00 ± 0.36 | 1.30 ± 0.20 | 0.85 ± 0.13 | 1.81 ± 0.29 | 1.00 ± 0.09 | 1.99 ± 0.13 | 2.90 ± 0.32 |
Suc | 1.00 ± 0.06 | 1.20 ± 0.17 | 0.92 ± 0.08 | 1.18 ± 0.17 | 1.00 ± 0.35 | 1.58 ± 0.15 | 0.87 ± 0.23 | 1.89 ± 0.28 | 1.00 ± 0.14 | 1.16 ± 0.14 | 1.22 ± 0.10 |
Fru-6-P | 1.00 ± 0.07 | 1.33 ± 0.10 | 1.50 ± 0.09 | 0.97 ± 0.04 | 1.00 ± 0.24 | 1.64 ± 0.19 | 1.38 ± 0.121 | 1.79 ± 0.16 | 1.00 ± 0.05 | 1.42 ± 0.07 | 1.65 ± 0.07 |
Glu-6-P | 1.00 ± 0.04 | 1.43 ± 0.10 | 1.55 ± 0.09 | 0.86 ± 0.02 | 1.00 ± 0.25 | 1.33 ± 0.13 | 1.10 ± 0.07 | 1.83 ± 0.11 | 1.00 ± 0.14 | 2.31 ± 0.12 | 2.82 ± 0.20 |
3-PGA | 1.00 ± 0.11 | 1.70 ± 0.12 | 2.04 ± 0.30 | 1.62 ± 0.42 | 1.00 ± 0.28 | 1.29 ± 0.15 | 1.30 ± 0.19 | 1.42 ± 0.31 | n.d. | n.d. | n.d. |
6-P-Gluconate | 1.00 ± 0.22 | 1.63 ± 0.40 | 0.86 ± 0.23 | 1.72 ± 0.53 | n.d. | n.d. | n.d. | n.d. | n.d. | n.d. | n.d. |
Phosphate | 1.00 ± 0.04 | 0.97 ± 0.03 | 0.92 ± 0.06 | 1.06 ± 0.02 | 1.00 ± 0.07 | 0.88 ± 0.07 | 0.80 ± 0.08 | 0.81 ± 0.06 | 1.00 ± 0.05 | 0.75 ± 0.06 | 0.57 ± 0.03 |
Data are normalized to the mean response calculated for the wild type of each measure batch. (To allow comparison between measure batches, individual wild-type values were normalized in the same way.) Values presented are the mean ± se of the mean of six independent determinants. Those that are significantly different from wild type are identified in bold type. n.d., Compounds that were not determined in a particular set of chromatograms; 3-PGA, 3-phosphoglyceric acid; GABA, 4-amino butyric acid.