Table 2.
Temperature values of steepest changes of FTIR band shifts recorded as function of temperature and middle frequencies of selected vibration bands at different periods of greening
Greening, h
|
Amide I | |||||
---|---|---|---|---|---|---|
T, °C | frequency, cm−1 | νsymCH2 | ||||
A | B | A | B | T, °C | frequency, cm−1 | |
0.5 | 35 | 40 | 1,654 | 1,624 | 52 | 2,850.2 |
6 | 35 | 40 | 1,656 | 1,626 | 53 | 2,849.6 |
12 | 39 | 41 | 1,656 | 1,629 | 55 | 2,849.8 |
24 | 41 | 41 | 1,656 | 1,630 | 52 | 2,850.3 |
48 | 44 | 43 | 1,658 | 1,632 | 48 | 2,850.2 |
Temperature of steepest changes on the parameter vs. temperature plots (cf. Fig. 5).
Values are given to significant digits.
Middle frequencies of amide (at 25°C) and νsymCH2 (at 34°C) bands.