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. 2003 Jun;84(6):3874–3882. doi: 10.1016/S0006-3495(03)75115-7

TABLE 2.

Cyclic peptide thermodynamic parameters of folding

Tm (°C) ΔT(°C) ΔHf (kJ/mol) ΔSf (J/mol·K)
6-mer* 37 387 −10 −31
10-mer 50.5 ± 0.3 139.4 ± 12.4 −29.1 ± 0.4 −89.8 ± 1.4
14-mer 71.0 ± 2.3 84.1 ± 5.0 −48.3 ± 0.5 −140.4 ± 1.8
*

The breadth of the transition in this case precludes a unique fit; included for comparative purposes only.

Standard deviations are reported. Thermodynamic parameters are derived from a two-state model and a van't Hoff analysis.