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The contributions of enthalpic and entropic effects to the stability (free energy change) of the 15-bp duplexes TGT (solid and open bars) and AGT (vertical and horizontal striped bars) containing the monofunctional adduct of [PtCl(dien)]Cl (solid bars; vertical striped bars) or [PtCl(NH3)3]Cl (open bars; horizontal striped bars). The units for each parameter (ΔΔHcal, TΔΔS, and ΔΔG25) are kcal/mol and T = 25°C.
