TABLE 1.
Duplex | Tm (°C) | ΔHcal (kcal/mol) | ΔS (cal/mol) | ΔHvH (kcal/mol) | ΔHvH/ΔHcal | ||
---|---|---|---|---|---|---|---|
TGT | 57.5 | 97.1 | 295.5 | 9.0 | 102.6 | 1.06 | 7.42 |
TGT-Pt(dien) | 49.5 | 79.9 | 248.6 | 5.8 | 93.8 | 1.17 | 5.86 |
TGT-Pt(NH3)3 | 49.4 | 81.9 | 254.2 | 6.1 | 93.0 | 1.14 | 5.94 |
AGT | 57.5 | 94.9 | 288.8 | 8.8 | 105.1 | 1.11 | 7.14 |
AGT-Pt(dien) | 55.6 | 88.7 | 271.1 | 7.9 | 101.7 | 1.15 | 5.74 |
AGT-Pt(NH3)3 | 53.6 | 85.0 | 262.6 | 6.7 | 91.2 | 1.07 | 5.46 |
The ΔH, ΔS, and values are averages derived from three independent experiments. The experimental uncertainties of the parameters are as follows: Tm (±0.5°C), ΔHcal (±2%), ΔS (±3%),