Table 2.

Initial rate kinetics experiments.

Entry	[1a]	[Pd]	ν1a [MS−1]	ν2a [MS−1]
1[a]	[0.01]	–	−2.61e−6 ± 1.46e−7	8.14e−7 ± 5.46e−8
2[b]	[0.01]	[0.001]	−2.51e−6 ± 7.90e−8	1.74e−6 ± 2.65e−7
3	[0.01]	[0.0005]	−2.59e−6 ± 5.77e−8	1.79e−6 ± 2.38e−7
4	[0.005]	[0.001]	−1.31e−6 ± 6.26e−8	9.63e−7 ± 5.52e−8
Entry	[7]	[Pd]	ν7 [MS−1]	–
5	[0.01]	–	−5.42e−7 ± 3.24e−8	–
6	[0.01]	[0.001]	−6.89e−7 ± 3.21e−8	–

^[a]ν_4a=1.28e⁻⁶ ± 9.70e⁻⁸;

^[b]ν_4a(Pd) below detection threshold for Pd-catalyzed reactions.