Table 2. Experimental (Exp) and theoretical (Theor) FRQ degradation rate constant values at 20°C and 25°C.
| FRQ1 |
FRQ+ |
FRQ7 |
FRQS5131 |
|||||
|---|---|---|---|---|---|---|---|---|
| Exp | Theor | Exp | Theor | Exp | Theor | Exp | Theor | |
| k (20°C)*, h-1 | 0.27 | 0.33 | 0.22 | 0.21 | 0.16 | 0.13 | 0.08 | 0.09 |
| k (25°C)*, h-1 | 0.33 | 0.41 | 0.27 | 0.26 | 0.22 | 0.18 | 0.12 | 0.13 |
| Ea (kJ/mol) | 29 | 30 | 46 | 59 | ||||
The theoretical k values at 20°C and 25°C are calculated from the (theoretical) k5 (=k6) FRQ degradation rate constants given in Table 1 by using the experimentally determined activation energies Ea and Eq. 1.