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. 2026 Jun 8. Online ahead of print. doi: 10.1039/d6sc01073c

Table 2. Experimental transition dipole moments (MAbsMID and MAbsICT) for 0F–3F, the SAN and Rabs values for 1F–3F and the calculated transition dipole moments (MCalcMID and MCalcICT) for 1F–3F.

N Experimental values Calculated values
M Abs (D)a [fosc]b M Abs (D)a [fosc]b S AN R abs M Calc (D)c M Calc (D)d
0F 3.50 [0.14] 3.93 [0.15]
1F 1 4.83 [0.26] 3.97 [0.15] 1.00 1.92 4.83 3.97
2F 2 6.98 [0.53] 5.22 [0.26] 1.05 2.18 6.83 5.61
3F 3 8.29 [0.74] 5.71 [0.31] 0.99 2.23 8.37 6.87
a

Calculated according to eqn (1).

b

Calculated according to eqn (2).

c

Calculated as the product of √N (where N is the number of monomers) and MAbsMID of 1F as the monomer. d Calculated as the product of √N (where N is the number of monomers) and MAbsICT of 1F as the monomer.

d

An updated Table 2 was attached in response to Q4.