Table 4. Ethenolysis of 14 promoted by catalysts 1, 2 and HGII.

Entry	Catalysta	Cat./14 (ppm)	Temperature (°C)	Conversionb (%)	Selectivityc (%)	Yieldd (%)	TONe
1	1a	500	50	79	84	67	1330
2	1b	500	50	64	79	51	1020
3	2a	500	50	86	87	75	1500
4	2b	500	50	80	94	74	1490
5	HGII	500	50	71	43	30	600
6	1a	50	50	15	76	12	2320
7	1b	50	50	18	81	15	2920
8	2a	50	50	30	76	23	4560
9	2b	50	50	14	99	14	2780
10	1a	50	70	12	73	9	1800
11	1b	50	70	13	73	9	1830
12	2a	50	70	70	92	65	12 920
13	2b	50	70	20	99	20	3920

^aThe reactions were conducted under neat conditions utilizing 5.4 mmol of 14 (90–95%) at a pressure of 10 bar of ethylene grade 3 for 3 h. Dodecane (150 µL) was used as an internal standard.

^bDetermined by GC analysis. Conversion = 100 − (final moles of 14) × 100/[initial moles of 14].

^cDetermined by GC analysis. Selectivity = 100 × (moles of ethenolysis products 15 + 16)/[(moles of 15 + 16) + (2 × (moles of 17 + 18))].

^dYield = conversion × selectivity/100.

^eTON = yield × (initial moles of 14/moles of catalyst)/100.