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. 2026 Mar 14;16:21020. doi: 10.1038/s41598-026-35873-z

Table 3.

Comparison between HCl and citric acid.

Property HCl Citric Acid
Acid Strength Strong (complete dissociation) Weak (partial dissociation)
Leaching Efficiency High, especially for base metals like Ni, Mn Moderate, effective for some metals (e.g., Mg, Fe)
Leaching Kinetics Faster leaching due to high acidity Slower leaching, especially for less soluble metals
Environmental Impact Higher, requires careful handling and disposal Lower, biodegradable and safer to handle
Corrosivity High, requires corrosion-resistant materials Low, less corrosion to equipment
Selectivity Less selective, effective for a wide range of metals Selective for metals that form stable complexes
Suitability for Multi-Stage Leaching Effective but may require more frequent replenishment Suitable, especially for more gentle extraction