Table 2. Comparison of results from one particular experiment (Roter et al., 2026 ▸) (with
from Section 3.5) against calculated values for mass concentrations
and detected number of fluorescent photons
per pixel, along with the number of incident photons
per pixel. As noted in Section 3.5, we did not have a direct measure of the air gap distance dg of equation (21); therefore, we show the ratio of experimental to theoretical incident photons
for the sample dsdp = 0.98 cm from the detector plane, as well as for a revised value of dsdp = 4.5 cm (see Section S4 of the supporting information).
| Element |
(µg cm−2) |
(photons per pixel) |
[equation (8)] (photons per pixel) (dsdp = 0.98 cm)(dg = 0.58 cm) |
(dsdp = 0.98 cm) (dg = 0.58 cm) |
(dsdp = 4.5 cm) (dg = 4.1 cm) |
|---|---|---|---|---|---|
| P | 9.893 | 3.64 | 2.9 × 106 | 132.5 | 1.44 |
| S | 1.853 | 5.08 | 1.1 × 107 | 35.0 | 0.79 |
| Ca | 0.073 | 3.54 | 3.5 × 107 | 10.9 | 0.70 |
| Fe | 0.025 | 4.11 | 2.9 × 107 | 13.2 | 1.18 |
| Ni | 0.010 | 2.83 | 3.4 × 107 | 11.5 | 1.05 |