Table 2. Putative antifungal candidates based on chemometrics and biochemometrics profiling of fractions in negative ion mode.

Feature (m/z_RT)	Adduct type	Putative ID	MS/MS spectrum	Class	Reported antifungal activity*
mz327.25415_19.306	[M-H]-	2,4-Dihydroxyheptadec-16-enyl acetate	89.02545 : 4076 193.49608 : 4437 206.62772 : 4068 215.65144 : 4152 242.98553 : 24353 255.23306 : 438856 262.99387 : 4615 286.99622 : 4384 326.99454 : 16492 327.18158 : 4486 327.25497 : 9773	Lipid/fatty acyl	Unknown
mz811.46448_20	[M+HCOO]-	Cauloside C	121.06588 : 10723 143.47859 : 4616 152.37431 : 4121 188.93207 : 4099 193.08763 : 6124 257.28659 : 4597 281.24908 : 77431 284.40451 : 4719 362.14395 : 4483 483.20160 : 6746 542.84064 : 4469 542.97668 : 5207 725.87927 : 5934 765.47131 : 5675 811.03723 : 12666 811.46045 : 25946	Triterpenoid saponin	Unknown

m/z_RT refers to mass to charge_retention time of the compounds.

MS/MS spectrum refers to fragment ions of the tentatively identified compounds.

^*Column ‘Antifungal’ refers to annotated antifungal activity based on published literature. ‘Unknown’ denotes that no studies were found that specifically tested the compound for its antifungal properties.