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Extended pathway for methionine and isoleucine biosynthesis in C. glutamicum. In addition to the reactions known before, the newly found side reactions of cystathionine-β-synthase (MetB) and cystathionine-β-lyase (MetC) leading to the formation and cleavage of homolanthionine, respectively, are shown. Further enzymes involved are MetA (homoserine transacetylase) and MetZ (O-acetylhomoserine sulfhydrolase).
