Fig. 2. Electrochemical properties and atomistic mechanisms of Na⁺ transport in COF/PNSE electrolyte.

a SEM image of the COF/PNSE. b Corresponding elemental mapping images. c EIS Nyquist plots of COF/PNSE at varying temperatures. d Temperature-dependent ionic conductivity of COF/PNSE. e Room-temperature ionic conductivity comparison between PNSE and COF/PNSE. f Activation energy (Ea) for Na+ migration in PNSE and COF/PNSE. g Temperature-dependent Na+ transference numbers for PNSE and COF/PNSE. h LSV curves of PNSE and COF/PNSE. i Molecular structure and electrostatic potential distribution of PVDF-TrFE-CFE copolymer. j Electrostatic potential distribution of the COF framework. k Calculated adsorption energies of Na+ with DMF, COF, TFSI⁻, PTC, and PVDF. l MD simulation snapshots of the PNSE system. m MD simulation snapshots of the COF/PNSE composite system. n Representative simulation snapshots of Na+ migration pathways in the COF/PNSE system at room temperature. o Mean squared displacement (MSD) of Na+ ions in COF/PNSE and PNSE systems derived from MD simulations.