Table 2.
EL performance parameters of NIR OLEDs based on the studied radicals
| Dopant (3 wt%) | Von a [V] | R/J at 12 V b [mW sr-1m−2/mA cm-2] | EQEmax c [%] | EQE J=1/10/100 c [%] | λEL d [nm] | R0 e [mW sr−1m−2] | LT85f [hour] |
|---|---|---|---|---|---|---|---|
| TTM-TPA | 2.7 | 60659/213 | 9.01 g | 8.89/8.22/6.54 | 798 | 40 | 4.0 |
| perD-TTM-TPA | 2.7 | 84429/271 | 10.81 | 10.65/9.50/7.75 | 800 | 48 | 14.0 |
| PyBTM-TPA | 2.8 | 34662/469 | 2.66 | 2.64/2.49/2.04 | 866 | 10 | 8.5 |
| perD-PyBTM-TPA | 3.0 | 57913/561 | 3.56 | 3.42/3.50/3.00 | 865 | 11 | 76.8 |
a The voltage at which the radiance reaches 1 mW sr–1 m–2.
bBoth the radiance and current density are measured at 12 V.
cThis value corresponds to the EQEmax and EQE determined at 1, 10, and 100 mA cm–2.
dEL spectra measured at 5 V.
eThe initial radiance values at the applied constant current density of 0.1 mA cm⁻².
fThe duration it takes for the EL intensity to decrease to 85% of its initial value.
gAn EQEmax of 9.6% was reported in ref. 37.
TTM-TPA, perD-TTM-TPA, PyBTM-TPA and perD-PyBTM-TPA.