Table 2.
13C NMR (100 MHz, CDCl3) data of compounds aknadinine (1), aknadilactam (2), aknadicine (3) (δ in ppm) and authentic aknadinine, aknadilactam and aknadicine
| Position | Aknadinine (1) | Authentic aknadinine21–23 | Aknadilactam (2) | Authentic aknadilactam21–23 |
Aknadicine (3) | Authentic aknadicine21–23 |
|---|---|---|---|---|---|---|
| 1 | 119.17 | 119.13 | 119.45 | 119.36 | 119.51 | 119.48 |
| 2 | 108.66 | 108.64 | 109.70 | 109.66 | 108.86 | 108.82 |
| 3 | 145.02 | 145.01 | 145.28 | 145.24 | 145.01 | 144.99 |
| 4 | 143.77 | 143.76 | 143.94 | 143.90 | 143.71 | 143.69 |
| 5 | 43.29 | 43.28 | 41.60 | 41.52 | 42.89 | 42.86 |
| 6 | 194.83 | 194.82 | 192.92 | 192.86 | 194.39 | 194.42 |
| 7 | 138.17 | 138.12 | 137.24 | 137.15 | 136.97 | 136.92 |
| 8 | 165.13 | 165.16 | 160.80 | 160.76 | 164.83 | 164.96 |
| 9 | 23.07 | 23.05 | 25.09 | 25.01 | 26.63 | 26.63 |
| 10 | 25.25 | 25.22 | 25.14 | 25.06 | 24.99 | 24.96 |
| 11 | 128.80 | 128.77 | 127.91 | 127.83 | 128.29 | 128.23 |
| 12 | 128.41 | 128.41 | 123.96 | 123.90 | 128.29 | 128.12 |
| 13 | 47.17 | 47.13 | 42.77 | 42.70 | 45.42 | 45.36 |
| 14 | 67.87 | 67.81 | 67.98 | 67.90 | 67.04 | 66.97 |
| 15 | 33.99 | 33.96 | 40.56 | 40.47 | 34.55 | 34.52 |
| 16 | 51.38 | 51.34 | 174.49 | 174.42 | 42.23 | 42.21 |
| 3-OMe | 56.24 | 56.22 | 56.29 | 56.22 | 56.25 | 56.22 |
| 7-OMe | 60.75 | 60.73 | 60.72 | 60.64 | 60.61 | 60.61 |
| 8-OMe | 60.57 | 60.55 | 61.01 | 60.95 | 61.26 | 61.25 |
| N-Me | 36.38 | 36.36 | 28.23 | 28.16 | - | - |
21–23, references