Fig. 1.
BIRD spectra of hexamethonium bromide (M2+·Br−)+ at a chamber temperature of 229 °C, with delay times of (a) 10 s and (b) 45 s. The isolated (M2+·Br−)+ ion (•) dissociates as shown in Scheme 1, to give species II (○) and species III (▴), which subsequently dissociates to give species IV (▵).