Table I.
Critical comparison of representative coke-reduction routes according to coke function, carbon-saving role, and industrial limitations
| Strategy | Main coke function targeted | Carbon-saving role | Key industrial limitation |
|---|---|---|---|
| Low-rank coal/semi-coke | Chemical demand reduction | Partial fossil carbon substitution | High reactivity; weak hot strength |
| Biomass/biochar/bio-coke | Chemical demand reduction | Lower net fossil CO2 input | Supply limitation, quality variation, weak structural role |
| Carbon-bearing wastes/by-products | Chemical demand reduction | Waste carbon recovery | Impurity accumulation, slag chemistry, permeability |
| Auxiliary fuel injection (especially PCI) | Chemical demand reduction | Reduces coke as fuel and reductant | Combustion efficiency, raceway stability, thermal balance |
| H2-rich gas injection | Chemical demand reduction | Lowers carbon-based reduction demand | H2 cost, thermal balance, H2O-induced coke degradation |
| Hot-blast temperature, oxygen enrichment, and high-pressure operation | Chemical demand reduction | Indirect coke saving | Limited by furnace stability and operating window |
| Top-gas recycling/oxygen blast furnace | Chemical demand reduction | High CO2-reduction potential | CO2 separation, O2 demand, energy penalty, system integration |
| Burden and furnace structure optimization | Indirect reduction of structural demand | Maintains permeability at lower coke rate | Ore quality, softening-melting control |
| CO2-to-CO conversion | Chemical demand reduction | Reuses captured CO2 as reducing gas | Conversion efficiency, energy demand, reactor integration |
| Load-bearing packed-bed materials | Direct structural support | Potential structural coke replacement | Slag attack, abrasion, cost, recyclability, large-scale supply |