Table 2. Overview of experimental conditions investigated to study the conditions affecting the formation of graphite-like carbon shells on Fe7C3 NPs.
| Entry | Fe(CO)5 | N,N-dimethylODA | ODA | CTAB | Atm. | Phase |
|---|---|---|---|---|---|---|
| Volume (mL) | Volume (mL) | Mass (g) | Mass (g) | |||
| Std | 1.4 | 30 | — | — | NH3 | Fe7C3@C |
| A | 1.4 | 20 | — | — | NH3 | Fe7C3@C |
| B | 1.4 | 40 | — | — | NH3 | Fe7C3@C |
| C | 1.4 | 30 | — | — | Ar | γ-Fe2O3 |
| D | 1.4 | 30 | — | 0.113 | Ar | Fe5C2 |
| E | 1.4 | — | 14.5 | — | NH3 | γ-Fe2O3 |
| F | 1.4 | — | 14.5 | 0.113 | NH3 | Fe5C2 |
| G | 1.4 | 30 | — | — | Ar : H2 | Fe7C3@C |
| 95 : 5 |