Table 1. Experimental details.
| Crystal data | |
| Chemical formula | Tl+·C32H12BF24− |
| M r | 1067.63 |
| Crystal system, space group | Tetragonal, P4/n |
| Temperature (K) | 100 |
| a, c (Å) | 13.4930 (4), 9.6227 (5) |
| V (Å3) | 1751.92 (12) |
| Z | 2 |
| Radiation type | Mo Kα |
| μ (mm−1) | 4.76 |
| Crystal size (mm) | 0.16 × 0.15 × 0.10 |
| Data collection | |
| Diffractometer | Bruker D8 VENTURE |
| Absorption correction | Multi-scan (SADABS; Bruker, 2016 ▸) |
| Tmin, Tmax | 0.633, 0.747 |
| No. of measured, independent and observed [I ≥ 2σ(I)] reflections | 87174, 3197, 2970 |
| R int | 0.055 |
| (sin θ/λ)max (Å−1) | 0.757 |
| Refinement | |
| R[F2 > 2σ(F2)], wR(F2), S | 0.021, 0.053, 1.06 |
| No. of reflections | 3197 |
| No. of parameters | 284 |
| No. of restraints | 697 |
| H-atom treatment | H atoms treated by a mixture of independent and constrained refinement |
| Δρmax, Δρmin (e Å−3) | 0.59, −0.86 |
Computer programs: APEX4 (Bruker, 2022 ▸), SAINT (Bruker, 2019 ▸), SHELXT (Sheldrick, 2015a ▸), SHELXL (Sheldrick, 2015b ▸), ShelXle (Hübschle et al., 2011 ▸), Mercury (Macrae et al., 2020 ▸), PLATON (Spek, 2020 ▸), enCIFer (Allen et al., 2004 ▸) and FinalCIF (Kratzert, 2026 ▸), OLEX2 (Dolomanov et al., 2009 ▸), olex2.refine (Bourhis et al., 2015 ▸) and VESTA 3 (Momma & Izumi, 2011 ▸).