TABLE 4.
The motionally averaged chemical shift tensor (Δδexp) for ergosterol ring carbons of the three lipid mixtures at 313 K
| DMPC/Ergosterol (mol/mol)
|
|||
|---|---|---|---|
| Carbon number | 8.4:1.6 | 7.7:2.3 | 7.0:3.0 |
| 1 | 0.0 ± 3* | 0.0 ± 3* | 0.0 ± 3* |
| 2 | 0.0 ± 3* | 0.0 ± 3* | 0.0 ± 3* |
| 3 | −24.0 ± 1.6† | −26.0 ± 1.6† | −27.9 ± 1.6† |
| 4 | −13.3 ± 3* | −13.3 ± 3† | −13.3 ± 3* |
| 5 | 63 ± 1.6† | 80.7 ± 1.6† | 80.7 ± 1.6† |
| 6 | 37.7 ± 1.6† | 44.7 ± 1.6† | 44.5 ± 1.6† |
| 7 | 41.7 ± 1.6† | 50 ± 1.6† | 50.1 ± 1.6† |
| 8 | 66 ± 1.6† | 72.7 ± 1.6† | 69.6 ± 1.6† |
| 9 | 0.0 ± 3* | 0.0 ± 3* | 0.0 ± 3* |
| 10 | 0.0 ± 3* | 0.0 ± 3* | 0.0 ± 3* |
| 11 | −3.3 ± 3* | −3.3 ± 3* | −3.3 ± 3* |
| 12 | 5 ± 3* | 5 ± 3* | 6.7 ± 3* |
| 13 | −3.3 ± 3* | −3.3 ± 3* | −6.7 ± 3* |
| 14 | −6.6 ± 3* | −6.6 ± 3* | −6.7 ± 3* |
| 15 | −10 ± 3* | −10 ± 3* | −10 ± 3* |
| 16 | ND | ND | ND |
| 17 | −15 ± 3* | −15 ± 3* | −20 ± 3* |
| 18 | 3.3 ± 3* | 3.3 ± 3* | 6.7 ± 3* |
| 19 | 13.3 ± 3* | 13.3 ± 3* | 16.7 ± 3* |
Experimental values were extracted from OMAS experiments.
Experimental values were extracted from slow MAS experiments.