TABLE 2.
Argon
|
Oxygen
|
NiEDDA
|
|||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Residue*†‡ | A11 | We1 | A12 | We2 | A21 | kex21 | A22 | kex22 | A31 | kex31 | A32 | kex32 | χ2§ |
128 | 90 | 0.235 | 11 | 0.235 | 11 | 0.0 | 70 | 2.19 | 25 | 0.0 | 66 | 0.265 | 1.66 |
129 | 58 | 0.065 | 40 | 0.155 | 62 | 0.21 | 30 | 0.289 | 80 | 0.01 | 17 | 0.108 | 1.03 |
130 | 4 | 0.21 | 97 | 0.21 | 1 | 0 | 96 | 1.58 | 14 | 0 | 85 | 0.14 | 2.00 |
131 | 1 | 0.25 | 99 | 0.25 | 8 | 0.00 | 94 | 1.96 | 7 | 0.0 | 93 | 0.19 | 1.57 |
132 | 8 | 0.16 | 92 | 0.27 | 41 | 3.21 | 57 | 1.23 | 5 | 0.0 | 83 | 0.25 | 1.58 |
133 | 41 | 0.095 | 58 | 0.05 | 90 | 0.00 | 7 | 0.635 | 5 | 0.025 | 94 | 0.002 | 1.25 |
134 | 52 | 0.105 | 45 | 0.165 | 2 | 0.135 | 74 | 1.61 | 8 | 0.00 | 85 | 0.132 | 2.11 |
135 | 48 | 0.16 | 47 | 0.31 | 28 | 0.00 | 57 | 1.69 | 25 | 0.00 | 46 | 0.3 | 1.61 |
We1 and We2 are in MHz; kex is in MHz/mM.
The specific exchange rate constants (kex) are obtained by dividing Wex values from fitting by the concentration of exchange reagent; 3 mM for NiEDDA and 0.26 mM for O2 in equilibrium with air (38).
Standard deviation from global fits is <0.1% and 1% for We and Wex, respectively.
From global fits.