Table 2. Thermodynamic parameters for CV adsorptiona.
| Adsorbents | T (K) | K L | ln KL | ΔG°-L (kJ mol−1) | ΔG°-NL (kJ mol−1) | ΔH°-L (kJ mol−1) | ΔH°-NL (kJ mol−1) | ΔS°-L (J mol−1 K−1) | ΔS°-NL (J mol−1 K−1) | R 2-L | R 2-NL |
|---|---|---|---|---|---|---|---|---|---|---|---|
| Mt-Ag/Sn@CeO2 | 298 | 22.766 | 3.1253 | −7.235 | −7.703 | −50.33 | −69.90 | −144.62 | −208.71 | 0.977 | 0.974 |
| 308 | 7.358 | 1.9958 | −5.788 | −5.615 | |||||||
| 318 | 4.627 | 1.5318 | −4.342 | −3.528 | |||||||
| 328 | 3.428 | 1.2319 | −2.896 | −1.441 | |||||||
| Ag/Sn@CeO2 | 298 | 8.106 | 2.0926 | −5.029 | −5.153 | −43.02 | −53.91 | −104.00 | −116.64 | 0.926 | 0.990 |
| 308 | 4.514 | 1.5072 | −3.989 | −3.987 | |||||||
| 318 | 2.772 | 1.0197 | −2.949 | −2.820 | |||||||
| 328 | 2.190 | 0.7841 | −1.909 | −1.654 |
K L is the Langmuir equilibrium constant obtained from isotherm fitting at each temperature. L = linear regression; NL = nonlinear regression.