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. 2026 Oct 19. Online ahead of print. doi: 10.1039/d6ra07930j

Table 2. Thermodynamic parameters for CV adsorptiona.

Adsorbents T (K) K L ln KL ΔG°-L (kJ mol−1) ΔG°-NL (kJ mol−1) ΔH°-L (kJ mol−1) ΔH°-NL (kJ mol−1) ΔS°-L (J mol−1 K−1) ΔS°-NL (J mol−1 K−1) R 2-L R 2-NL
Mt-Ag/Sn@CeO2 298 22.766 3.1253 −7.235 −7.703 −50.33 −69.90 −144.62 −208.71 0.977 0.974
308 7.358 1.9958 −5.788 −5.615
318 4.627 1.5318 −4.342 −3.528
328 3.428 1.2319 −2.896 −1.441
Ag/Sn@CeO2 298 8.106 2.0926 −5.029 −5.153 −43.02 −53.91 −104.00 −116.64 0.926 0.990
308 4.514 1.5072 −3.989 −3.987
318 2.772 1.0197 −2.949 −2.820
328 2.190 0.7841 −1.909 −1.654
a

K L is the Langmuir equilibrium constant obtained from isotherm fitting at each temperature. L = linear regression; NL = nonlinear regression.