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. Author manuscript; available in PMC: 2006 Mar 22.
Published in final edited form as: J Am Chem Soc. 1999 Feb 24;121(7):1565–1573. doi: 10.1021/ja982653+

Figure 3.

Figure 3

Experimental (open symbols) and calculated (filled symbols) values of IP(M+), D°0(M+–OH), and D°0(M2+–OH−) that are used in the thermochemical cycles (eqs 3 and 3’), as a function of the M–O1 distance in MOH+. The value of D°0(M2+–OH−) smoothly follows the Coulomb energy of a double and a single charge at distance r (solid line).