TABLE 1.
Measured Zero-Pressure Limit Arrhenius Parameters, Parameters Used in the Master Equation Modeling of These Data, and the Resulting Range of E0 for the Trimers (Base2TFA + H)+
| base | Ea (eV) | Log A | μ01 scaling factor | E0 range (eV) | modeled log A∞ range | E0 (eV) |
|---|---|---|---|---|---|---|
| MTBD | 1.30 ± 0.04 | 16.5 ± 0.5 | 3 | 1.42 ± 0.03 | ||
| 4 | 1.40–1.45 | 18–19 | ||||
| 5 | 1.39–1.42 | 17.5–19 | ||||
| TBD | 1.08 ± 0.03 | 13.0 ± 0.4 | 3 | 1.42 ± 0.04 | ||
| 4 | 1.40–1.46 | 17.5–19 | ||||
| 5 | 1.38–1.43 | 16–19 | ||||
| DBU | 0.88 ± 0.02 | 11.6 ± 0.3 | 3 | 1.20 ± 0.05 | ||
| 4 | 1.19–1.25 | 17–19 | ||||
| 5 | 1.15–1.21 | 16–19 | ||||
| DBN | 0.76 ± 0.02 | 10.1 ± 0.4 | 3 | 1.09 ± 0.05 | ||
| 4 | 1.05–1.13 | 16–19 | ||||
| 5 | 1.04–1.13 | 16–19 | ||||
| TMG | 0.89 ± 0.01 | 12.3 ± 0.2 | 3 | 1.25 | 19 | 1.20 ± 0.05 |
| 4 | 1.15–1.23 | 16.5–19 | ||||
| 5 |