Table 1.
Aldehyde and common probe | UV absorption |
Fluorescence |
||||
---|---|---|---|---|---|---|
λmax (nm) | εmaxa | Ex (nm)b | Emmax (nm)c | Stokes' shift (nm) | Relative intensityd | |
2-Naphthaldehyde | 292 | 12.7 | 344 | 444 | 100 | 100 |
6-Methoxy-2-naphthaldehyde | 314 | 19.1 | 330 | 460 | 130 | 260 |
Pyrene-1-carbaldehyde | 397 | 9.8 | 397 | 470 | 73 | 246 |
9H-Fluorene-2-carbaldehyde | 318 | 34.6 | 330 | 409 | 79 | 188 |
6-Dimethylamino-2-naphthaldehyde | 377 | 18.4 | 396 | 528 | 132 | 173 |
Anthracene-9-carbaldehyde | 408 | 6.7 | 410 | 519 | 109 | 106 |
10-Methyl-anthracene-9-carbaldehyde | 425 | 9.1 | 399 | 531 | 132 | 26 |
Phenanthrene-9-carbaldehyde | 318 | 13.2 | 334 | 471 | 137 | 25 |
10-Chloro-antharacene-9-carbaldehyde | 437 | 6.0 | 410 | 532 | 122 | 22 |
3-(4-Nitro-phenyl)-propenal | 308 | 27.0 | 397 | 460 | 63 | 9 |
3-(4-Dimethylamino-phenyl)-propenal | 399 | 41.1 | 397 | 494 | 97 | 5 |
4-Quinoline-carbaldehyde | 315 | 3.6 | 335 | 430 | 95 | 5 |
5-(4-Dimethylamino-phenyl)-penta-2,4-dienal | 409 | 31.1 | 418 | 593 | 175 | 5 |
2-Quinoline-carbaldehyde | 301 | 5.7 | 346 | 420 | 74 | 4 |
4-Dimethylamino-benzaldehyde | 354 | 33.7 | 330 | 410 | 80 | 3 |
3-Quinoline-carbaldehyde | 292 | 10.6 | 345 | 430 | 85 | 2 |
Resorufin | 571 | 64.55 | 571 | 581 | 10 | 275 |
7-Hydroxy-4-trifluoromethyl coumarin | 341 | 11.11 | 356 | 496 | 140 | 276 |
Note. The data were obtained in 0.1 M sodium phosphate buffer (pH 7.8).
Molar absorptivity (103 M−1 cm−1).
Ex: optical excitation wavelength.
Emmax: maximal emission wavelength.
Relative intensity: fluorescent intensity of 2-NA is 100.